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Dataset for Metal-Organic Fireworks! MOFs as Structural Scaffolds for Pyrotechnic Materials

Dataset for Metal-Organic Fireworks! MOFs as Structural Scaffolds for Pyrotechnic Materials
Dataset for Metal-Organic Fireworks! MOFs as Structural Scaffolds for Pyrotechnic Materials
A new approach to formulating pyrotechnic materials is presented whereby constituent ingredients are bound together in a solid-state lattice in the form of a Metal-Organic Framework. This reduces the batch inconsistencies arising from the traditional approach of combining powders by ensuring the key ingredients are ‘mixed’ in stoichiometric quantities and are in intimate contact. Further benefits for the application of these types of material are increased safety levels as well as simpler logistics, storage and manufacture. A systematic series of new frameworks comprising fuel and oxidiser agents (group 1 and 2 metal nodes and terephthalic acid derivatives as linkers) has been synthesised and structurally characterised. These new materials have been assessed for pyrotechnic effect by calorimetry and burn tests. Results indicate that these materials exhibit the desired properties of a pyrotechnic mate-rial and that the effect can be correlated to the di-mensionality of the structure.
University of Southampton
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Blair, Lisa H.
113d29cf-809a-4c84-9e9f-ad8556d46cff
Sinclair, Ian
6005f6c1-f478-434e-a52d-d310c18ade0d
Colakel, Ayhan
61343a36-5181-42d9-bd2f-8cad7cd95264
Vrcelj, Ranko
4564df66-f6d3-4240-b369-eb96c7a70b50
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Blair, Lisa H.
113d29cf-809a-4c84-9e9f-ad8556d46cff
Sinclair, Ian
6005f6c1-f478-434e-a52d-d310c18ade0d
Colakel, Ayhan
61343a36-5181-42d9-bd2f-8cad7cd95264
Vrcelj, Ranko
4564df66-f6d3-4240-b369-eb96c7a70b50

Coles, Simon J., Blair, Lisa H., Sinclair, Ian, Colakel, Ayhan and Vrcelj, Ranko (2015) Dataset for Metal-Organic Fireworks! MOFs as Structural Scaffolds for Pyrotechnic Materials. University of Southampton doi:10.5258/SOTON/376152 [Dataset]

Record type: Dataset

Abstract

A new approach to formulating pyrotechnic materials is presented whereby constituent ingredients are bound together in a solid-state lattice in the form of a Metal-Organic Framework. This reduces the batch inconsistencies arising from the traditional approach of combining powders by ensuring the key ingredients are ‘mixed’ in stoichiometric quantities and are in intimate contact. Further benefits for the application of these types of material are increased safety levels as well as simpler logistics, storage and manufacture. A systematic series of new frameworks comprising fuel and oxidiser agents (group 1 and 2 metal nodes and terephthalic acid derivatives as linkers) has been synthesised and structurally characterised. These new materials have been assessed for pyrotechnic effect by calorimetry and burn tests. Results indicate that these materials exhibit the desired properties of a pyrotechnic mate-rial and that the effect can be correlated to the di-mensionality of the structure.

Text
Metal_Organic_Fireworks_Supporting_info.pdf - Text
Available under License Data: Open Database License (ODbL) (Attribution-Share Alike).
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Archive
Metal_Organic_Fireworks_SI_data.zip - Dataset
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More information

Published date: 2015
Organisations: Characterisation and Analytics, Engineering Mats & Surface Engineerg Gp, Chemistry

Identifiers

Local EPrints ID: 376152
URI: http://eprints.soton.ac.uk/id/eprint/376152
PURE UUID: 5eba75f3-1bf7-49b4-97e4-fc3f860a6b73
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 17 Apr 2015 09:23
Last modified: 13 Dec 2021 02:45

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Contributors

Creator: Simon J. Coles ORCID iD
Creator: Lisa H. Blair
Creator: Ian Sinclair
Creator: Ayhan Colakel
Creator: Ranko Vrcelj

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