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Divalent ytterbium complexes with crown and heterocrown ethers

Divalent ytterbium complexes with crown and heterocrown ethers
Divalent ytterbium complexes with crown and heterocrown ethers
Several unusual complexes of ytterbium(II) stabilised by coordination to mixed O4X2-donor macrocyclic ligands (X = O, NH, S or Se) are described. Distorted 8-coordination is evident from the crystal structure of the neutral [YbI2([18]aneO4Se2)], forming the first reported example of Yb(II)-selenoether coordination.
0300-9246
2953-2955
Bartlett, Philip N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Champion, Martin
4fecac1b-031e-45ea-ad7e-334d4da16f47
Light, Mark. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Richardson, Peter W.
babd5d43-0ea3-4a27-b92f-820683acd781
Bartlett, Philip N.
d99446db-a59d-4f89-96eb-f64b5d8bb075
Champion, Martin
4fecac1b-031e-45ea-ad7e-334d4da16f47
Light, Mark. E.
cf57314e-6856-491b-a8d2-2dffc452e161
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Richardson, Peter W.
babd5d43-0ea3-4a27-b92f-820683acd781

Bartlett, Philip N., Champion, Martin, Light, Mark. E., Levason, William, Reid, Gillian and Richardson, Peter W. (2015) Divalent ytterbium complexes with crown and heterocrown ethers. Dalton Transactions, 44 (7), 2953-2955. (doi:10.1039/C4DT03462G).

Record type: Article

Abstract

Several unusual complexes of ytterbium(II) stabilised by coordination to mixed O4X2-donor macrocyclic ligands (X = O, NH, S or Se) are described. Distorted 8-coordination is evident from the crystal structure of the neutral [YbI2([18]aneO4Se2)], forming the first reported example of Yb(II)-selenoether coordination.

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More information

Accepted/In Press date: 1 December 2014
e-pub ahead of print date: 2 December 2014
Published date: 21 February 2015
Organisations: Electrochemistry

Identifiers

Local EPrints ID: 376460
URI: http://eprints.soton.ac.uk/id/eprint/376460
ISSN: 0300-9246
PURE UUID: 7330f4d9-b359-415c-8a41-9b886cd52408
ORCID for Philip N. Bartlett: ORCID iD orcid.org/0000-0002-7300-6900
ORCID for Mark. E. Light: ORCID iD orcid.org/0000-0002-0585-0843
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 28 Apr 2015 14:22
Last modified: 20 Jul 2019 01:28

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Contributors

Author: Martin Champion
Author: Mark. E. Light ORCID iD
Author: William Levason ORCID iD
Author: Gillian Reid ORCID iD
Author: Peter W. Richardson

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