Potter, Matthew, Cholerton, Mary E., Kezina, Julija, Bounds, Richard, Carravetta, Marina, Manzoli, Maela, Gianotti, Enrica, Lefenfeld, Michael and Raja, Robert (2014) Role of isolated acid sites and influence of pore diameter in the low-temperature dehydration of ethanol. ACS Catalysis, 4 (11), 4161-4169. (doi:10.1021/cs501092b).
Abstract
Silicoaluminophosphates, SAPO-5 and SAPO-34, differ not only in their pore diameters and structural topology but also in their preferred mechanism of silicon substitution into the framework, which subsequently influences the nature of the acid sites for solid-acid-catalyzed transformations. This study combines 29Si NMR, FTIR, and DFT calculations for probing the nature of the isolated acid sites, thereby affording structure–property correlations, in the low-temperature catalytic dehydration of ethanol to ethylene.
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- Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Chemistry (pre 2018 reorg) > FIMS (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Chemistry > Chemistry (pre 2018 reorg) > FIMS (pre 2018 reorg)
School of Chemistry > Chemistry (pre 2018 reorg) > FIMS (pre 2018 reorg) - Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Chemistry (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Chemistry > Chemistry (pre 2018 reorg)
School of Chemistry > Chemistry (pre 2018 reorg) - Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Chemistry (pre 2018 reorg) > Chemistry Technical (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Chemistry > Chemistry (pre 2018 reorg) > Chemistry Technical (pre 2018 reorg)
School of Chemistry > Chemistry (pre 2018 reorg) > Chemistry Technical (pre 2018 reorg)
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