Role of isolated acid sites and influence of pore diameter in the low-temperature dehydration of ethanol
Role of isolated acid sites and influence of pore diameter in the low-temperature dehydration of ethanol
Silicoaluminophosphates, SAPO-5 and SAPO-34, differ not only in their pore diameters and structural topology but also in their preferred mechanism of silicon substitution into the framework, which subsequently influences the nature of the acid sites for solid-acid-catalyzed transformations. This study combines 29Si NMR, FTIR, and DFT calculations for probing the nature of the isolated acid sites, thereby affording structure–property correlations, in the low-temperature catalytic dehydration of ethanol to ethylene.
4161-4169
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Cholerton, Mary E.
517df6b5-2986-449c-8628-aee942432aaf
Kezina, Julija
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Bounds, Richard
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Carravetta, Marina
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Manzoli, Maela
a17ae924-77c3-47b3-8c3b-d1b29cac758a
Gianotti, Enrica
2496d8d3-780f-4fe0-a43e-147e68331078
Lefenfeld, Michael
01494715-6cee-47e2-bf55-18acd8be8f62
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
7 November 2014
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Cholerton, Mary E.
517df6b5-2986-449c-8628-aee942432aaf
Kezina, Julija
e4207217-45a7-4b24-a1b2-2436ce4a80fd
Bounds, Richard
3f108fd4-8375-4d0d-8718-e8be7a0ef7f7
Carravetta, Marina
1b12fa96-4a6a-4689-ab3b-ccc68f1d7691
Manzoli, Maela
a17ae924-77c3-47b3-8c3b-d1b29cac758a
Gianotti, Enrica
2496d8d3-780f-4fe0-a43e-147e68331078
Lefenfeld, Michael
01494715-6cee-47e2-bf55-18acd8be8f62
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Potter, Matthew, Cholerton, Mary E., Kezina, Julija, Bounds, Richard, Carravetta, Marina, Manzoli, Maela, Gianotti, Enrica, Lefenfeld, Michael and Raja, Robert
(2014)
Role of isolated acid sites and influence of pore diameter in the low-temperature dehydration of ethanol.
ACS Catalysis, 4 (11), .
(doi:10.1021/cs501092b).
Abstract
Silicoaluminophosphates, SAPO-5 and SAPO-34, differ not only in their pore diameters and structural topology but also in their preferred mechanism of silicon substitution into the framework, which subsequently influences the nature of the acid sites for solid-acid-catalyzed transformations. This study combines 29Si NMR, FTIR, and DFT calculations for probing the nature of the isolated acid sites, thereby affording structure–property correlations, in the low-temperature catalytic dehydration of ethanol to ethylene.
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e-pub ahead of print date: 10 October 2014
Published date: 7 November 2014
Organisations:
Chemistry
Identifiers
Local EPrints ID: 376621
URI: http://eprints.soton.ac.uk/id/eprint/376621
ISSN: 2155-5435
PURE UUID: f522b48c-0186-4852-9d6e-e284bd8d5297
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Date deposited: 06 May 2015 10:48
Last modified: 18 Feb 2021 17:16
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Contributors
Author:
Mary E. Cholerton
Author:
Julija Kezina
Author:
Richard Bounds
Author:
Maela Manzoli
Author:
Enrica Gianotti
Author:
Michael Lefenfeld
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