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Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from ?-Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands

Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from ?-Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands
Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from ?-Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands
The development of lanthanide “peptide” bundles from ?-amino acid functionalized 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligands is described, using either Eu(III)- or Tb(III)-directed synthesis. These ligands form stable and luminescent 1:3 (Ln:L) stoichiometric complexes in CH3CN upon the addition of 0.33 equiv of Ln(III); the Tb(III) bundles, in particular, are highly luminescent with quantum yields of up to 70%.
0020-1669
1426-1439
Byrne, Joseph P.
2eeef5fe-8784-435f-98dd-c9c1635f2ebf
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
O’Brien, John E.
49a7df75-b3e3-476f-bab2-55715c96b8c9
Peacock, Robert D.
cf938797-c8b4-43f6-b49d-6af680d03e3c
Gunnlaugsson, Thorfinnur
bbfcaaa6-2aca-47c9-9b7b-954442218f50
Byrne, Joseph P.
2eeef5fe-8784-435f-98dd-c9c1635f2ebf
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
O’Brien, John E.
49a7df75-b3e3-476f-bab2-55715c96b8c9
Peacock, Robert D.
cf938797-c8b4-43f6-b49d-6af680d03e3c
Gunnlaugsson, Thorfinnur
bbfcaaa6-2aca-47c9-9b7b-954442218f50

Byrne, Joseph P., Kitchen, Jonathan A., O’Brien, John E., Peacock, Robert D. and Gunnlaugsson, Thorfinnur (2015) Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from ?-Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands. Inorganic Chemistry, 54 (4), 1426-1439. (doi:10.1021/ic502384w).

Record type: Article

Abstract

The development of lanthanide “peptide” bundles from ?-amino acid functionalized 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligands is described, using either Eu(III)- or Tb(III)-directed synthesis. These ligands form stable and luminescent 1:3 (Ln:L) stoichiometric complexes in CH3CN upon the addition of 0.33 equiv of Ln(III); the Tb(III) bundles, in particular, are highly luminescent with quantum yields of up to 70%.

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More information

e-pub ahead of print date: 29 January 2015
Published date: 29 January 2015
Organisations: Chemistry, Faculty of Natural and Environmental Sciences, Organic Chemistry: SCF

Identifiers

Local EPrints ID: 377040
URI: https://eprints.soton.ac.uk/id/eprint/377040
ISSN: 0020-1669
PURE UUID: ebb11856-ac03-4737-a2ce-16be614221eb
ORCID for Jonathan A. Kitchen: ORCID iD orcid.org/0000-0002-7139-5666

Catalogue record

Date deposited: 14 May 2015 11:15
Last modified: 04 Jul 2018 16:31

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