Sodium thioether macrocyclic chemistry: remarkable homoleptic octathia coordination to Na+
Sodium thioether macrocyclic chemistry: remarkable homoleptic octathia coordination to Na+
Unprecedented homoleptic octathioether macrocyclic coordination to Na+ in [Na([24]aneS8)]+ has been achieved by using Na[B{3,5-(CF3)2-C6H3}4] as a source of “naked” Na+ ions and confirmed crystallographically, with d(Na–S) = 2.9561(15)–3.0524(15) Å. Density functional theory calculations show that there is electron transfer from the S 3p and C 2p valence orbitals of the ligand to the 3s and 3p orbitals of the Na+ ion upon complexation.
2497-2499
Champion, Martin J.D.
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Dyke, John M.
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Levason, William
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Light, Mark E.
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Pugh, David
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Bhakhoa, Hanusha
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Rhyman, Lydia
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Ramasami, Ponnadurai
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Reid, Gillian
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16 March 2015
Champion, Martin J.D.
98cc19c4-7e89-45e7-9ccb-233b44f662f9
Dyke, John M.
46393b45-6694-46f3-af20-d7369d26199f
Levason, William
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Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Pugh, David
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Bhakhoa, Hanusha
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Rhyman, Lydia
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Ramasami, Ponnadurai
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Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Champion, Martin J.D., Dyke, John M., Levason, William, Light, Mark E., Pugh, David, Bhakhoa, Hanusha, Rhyman, Lydia, Ramasami, Ponnadurai and Reid, Gillian
(2015)
Sodium thioether macrocyclic chemistry: remarkable homoleptic octathia coordination to Na+.
Inorganic Chemistry, 54 (6), .
(doi:10.1021/acs.inorgchem.5b00156).
Abstract
Unprecedented homoleptic octathioether macrocyclic coordination to Na+ in [Na([24]aneS8)]+ has been achieved by using Na[B{3,5-(CF3)2-C6H3}4] as a source of “naked” Na+ ions and confirmed crystallographically, with d(Na–S) = 2.9561(15)–3.0524(15) Å. Density functional theory calculations show that there is electron transfer from the S 3p and C 2p valence orbitals of the ligand to the 3s and 3p orbitals of the Na+ ion upon complexation.
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acs.inorgchem.5b00156
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e-pub ahead of print date: 27 February 2015
Published date: 16 March 2015
Organisations:
Chemistry
Identifiers
Local EPrints ID: 378798
URI: http://eprints.soton.ac.uk/id/eprint/378798
ISSN: 0020-1669
PURE UUID: 5d812a8a-15ce-45b1-bc22-751701d73365
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Date deposited: 07 Jul 2015 10:29
Last modified: 15 Mar 2024 03:01
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Contributors
Author:
Martin J.D. Champion
Author:
David Pugh
Author:
Hanusha Bhakhoa
Author:
Lydia Rhyman
Author:
Ponnadurai Ramasami
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