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Sodium thioether macrocyclic chemistry: remarkable homoleptic octathia coordination to Na+

Sodium thioether macrocyclic chemistry: remarkable homoleptic octathia coordination to Na+
Sodium thioether macrocyclic chemistry: remarkable homoleptic octathia coordination to Na+
Unprecedented homoleptic octathioether macrocyclic coordination to Na+ in [Na([24]aneS8)]+ has been achieved by using Na[B{3,5-(CF3)2-C6H3}4] as a source of “naked” Na+ ions and confirmed crystallographically, with d(Na–S) = 2.9561(15)–3.0524(15) Å. Density functional theory calculations show that there is electron transfer from the S 3p and C 2p valence orbitals of the ligand to the 3s and 3p orbitals of the Na+ ion upon complexation.
0020-1669
2497-2499
Champion, Martin J.D.
98cc19c4-7e89-45e7-9ccb-233b44f662f9
Dyke, John M.
46393b45-6694-46f3-af20-d7369d26199f
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Pugh, David
9ec61267-ae4d-40d8-bebf-0d603e2588d3
Bhakhoa, Hanusha
1a26ab2f-484e-4e54-803c-0e35af679ead
Rhyman, Lydia
d025e9f5-e723-49fd-ad1c-0a0508e6eb8a
Ramasami, Ponnadurai
5401f300-4ad3-4d35-8762-822768d6bd0c
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Champion, Martin J.D.
98cc19c4-7e89-45e7-9ccb-233b44f662f9
Dyke, John M.
46393b45-6694-46f3-af20-d7369d26199f
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Pugh, David
9ec61267-ae4d-40d8-bebf-0d603e2588d3
Bhakhoa, Hanusha
1a26ab2f-484e-4e54-803c-0e35af679ead
Rhyman, Lydia
d025e9f5-e723-49fd-ad1c-0a0508e6eb8a
Ramasami, Ponnadurai
5401f300-4ad3-4d35-8762-822768d6bd0c
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037

Champion, Martin J.D., Dyke, John M., Levason, William, Light, Mark E., Pugh, David, Bhakhoa, Hanusha, Rhyman, Lydia, Ramasami, Ponnadurai and Reid, Gillian (2015) Sodium thioether macrocyclic chemistry: remarkable homoleptic octathia coordination to Na+. Inorganic Chemistry, 54 (6), 2497-2499. (doi:10.1021/acs.inorgchem.5b00156).

Record type: Article

Abstract

Unprecedented homoleptic octathioether macrocyclic coordination to Na+ in [Na([24]aneS8)]+ has been achieved by using Na[B{3,5-(CF3)2-C6H3}4] as a source of “naked” Na+ ions and confirmed crystallographically, with d(Na–S) = 2.9561(15)–3.0524(15) Å. Density functional theory calculations show that there is electron transfer from the S 3p and C 2p valence orbitals of the ligand to the 3s and 3p orbitals of the Na+ ion upon complexation.

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e-pub ahead of print date: 27 February 2015
Published date: 16 March 2015
Organisations: Chemistry

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Local EPrints ID: 378798
URI: http://eprints.soton.ac.uk/id/eprint/378798
ISSN: 0020-1669
PURE UUID: 5d812a8a-15ce-45b1-bc22-751701d73365
ORCID for John M. Dyke: ORCID iD orcid.org/0000-0002-9808-303X
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

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Date deposited: 07 Jul 2015 10:29
Last modified: 03 Dec 2019 02:07

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Contributors

Author: Martin J.D. Champion
Author: John M. Dyke ORCID iD
Author: William Levason ORCID iD
Author: Mark E. Light ORCID iD
Author: David Pugh
Author: Hanusha Bhakhoa
Author: Lydia Rhyman
Author: Ponnadurai Ramasami
Author: Gillian Reid ORCID iD

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