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Expanding the scope of metal-free enantioselective allylic substitutions: Anthrones

Expanding the scope of metal-free enantioselective allylic substitutions: Anthrones
Expanding the scope of metal-free enantioselective allylic substitutions: Anthrones
The highly enantioselective asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.
1-9
Ceban, Victor
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Tauchman, Jiri
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Meazza, Marta
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Gallagher, Greg
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Light, Mark E.
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Gergelitsová, Ivana
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Veselý, Jan
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Rios, Ramon
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Ceban, Victor
2e53f2b7-42ff-4c26-96e9-ef75891af166
Tauchman, Jiri
6b0f31cb-27c6-4702-84ce-cef00090928e
Meazza, Marta
c4665645-8c77-4cfd-aa02-6bcc3341c1aa
Gallagher, Greg
d23049bc-3658-4236-b4fa-c5283c1915b1
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Gergelitsová, Ivana
87fd0763-2e36-46a9-b25c-573f18d869ba
Veselý, Jan
9d4ecc53-859e-451a-a018-636d416bb3fe
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441

Ceban, Victor, Tauchman, Jiri, Meazza, Marta, Gallagher, Greg, Light, Mark E., Gergelitsová, Ivana, Veselý, Jan and Rios, Ramon (2015) Expanding the scope of metal-free enantioselective allylic substitutions: Anthrones. Scientific Reports, 5 (16886), 1-9. (doi:10.1038/srep16886).

Record type: Article

Abstract

The highly enantioselective asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.

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More information

Accepted/In Press date: 19 October 2015
Published date: 23 November 2015
Organisations: Chemistry
Learn more about Chemistry research

Identifiers

Local EPrints ID: 385722
URI: http://eprints.soton.ac.uk/id/eprint/385722
DOI: doi:10.1038/srep16886
PURE UUID: 7719a098-2785-4f01-b5ab-b7719f25bbc1
ORCID for Marta Meazza: ORCID iD orcid.org/0000-0003-4382-0626
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 21 Jan 2016 13:55
Last modified: 15 Mar 2024 03:01

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Contributors

Author: Victor Ceban
Author: Jiri Tauchman
Author: Marta Meazza ORCID iD
Author: Greg Gallagher
Author: Mark E. Light ORCID iD
Author: Ivana Gergelitsová
Author: Jan Veselý
Author: Ramon Rios ORCID iD

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