The University of Southampton
University of Southampton Institutional Repository

Carboxylate complexation by a family of easy-to-make ortho-phenylenediamine based bis-ureas: studies in solution and the solid state

Carboxylate complexation by a family of easy-to-make ortho-phenylenediamine based bis-ureas: studies in solution and the solid state
Carboxylate complexation by a family of easy-to-make ortho-phenylenediamine based bis-ureas: studies in solution and the solid state
Simple bis-urea compounds based on ortho-phenylenediamine function as excellent receptors for carboxylate anions in DMSO-d(6)-0.5% water solution. By varying the functional groups in these compounds, the binding affinity of carboxylate anions can be modulated. Solid-state studies illustrate the cleft-like arrangement of the DDDD hydrogen bond array in the carboxylate complexes of these compounds.
ion-pair, anion receptors, recognition properties, molecular recognition, selective binding, sensor, deprotonation, chemosensors, derivatives, template
1144-0546
65-70
Brooks, Simon J.
fcf66c9a-5e4d-47cf-bc9f-e7c8886a061a
Edwards, Peter R.
aaa0f75a-0fd5-490a-ba73-a420189e4695
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Brooks, Simon J.
fcf66c9a-5e4d-47cf-bc9f-e7c8886a061a
Edwards, Peter R.
aaa0f75a-0fd5-490a-ba73-a420189e4695
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161

Brooks, Simon J., Edwards, Peter R., Gale, Philip A. and Light, Mark E. (2006) Carboxylate complexation by a family of easy-to-make ortho-phenylenediamine based bis-ureas: studies in solution and the solid state. New Journal of Chemistry, 30 (1), 65-70. (doi:10.1039/b511963d).

Record type: Article

Abstract

Simple bis-urea compounds based on ortho-phenylenediamine function as excellent receptors for carboxylate anions in DMSO-d(6)-0.5% water solution. By varying the functional groups in these compounds, the binding affinity of carboxylate anions can be modulated. Solid-state studies illustrate the cleft-like arrangement of the DDDD hydrogen bond array in the carboxylate complexes of these compounds.

Full text not available from this repository.

More information

Published date: 2006
Keywords: ion-pair, anion receptors, recognition properties, molecular recognition, selective binding, sensor, deprotonation, chemosensors, derivatives, template

Identifiers

Local EPrints ID: 39091
URI: https://eprints.soton.ac.uk/id/eprint/39091
ISSN: 1144-0546
PURE UUID: 06def683-56e0-4291-8df7-013cf002b9d2
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 20 Jun 2006
Last modified: 06 Jun 2018 12:54

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of https://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×