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Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides

Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides
Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides
The reaction of tricyclohexylphosphine with the S-based palladacycle [{Pd(?-OAc)(?(2)-S, C-C6H4CH2SMe)}(2)] gives several products, regardless of stoichiometry, one of which, [Pd(?(1)-OAc)(?(1)-C6H4CH2SMe)(PCy3)(2)], has been characterised crystallographically. Despite this, catalysts formed in situ from di- and tri-alkylphosphines and [{Pd(?-OAc)(?(2)-S, C-C6H4CH2SMe)}(2)] show excellent activity in the Suzuki coupling of a range of deactivated, non-activated and activated aryl chloride substrates.
highly efficient catalysts, triarylphosphite complexes, phosphinite complexes, active catalysts, heck reactions, c-c, palladium, ligand, water, coordination
1477-9226
3864-3868
Bedford, Robin B.
42532c45-cb80-48cd-9e93-8c2d5059eabe
Cazin, Catherine S. J.
c299b00c-24b5-4f80-81b4-145b9310b599
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Scordia, Véronique J. M.
38115eef-1562-41fb-a5a6-bef4fc164fdc
Bedford, Robin B.
42532c45-cb80-48cd-9e93-8c2d5059eabe
Cazin, Catherine S. J.
c299b00c-24b5-4f80-81b4-145b9310b599
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Scordia, Véronique J. M.
38115eef-1562-41fb-a5a6-bef4fc164fdc

Bedford, Robin B., Cazin, Catherine S. J., Hursthouse, Michael B., Light, Mark E. and Scordia, Véronique J. M. (2004) Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides. Dalton Transactions, (22), 3864-3868. (doi:10.1039/B407922C).

Record type: Article

Abstract

The reaction of tricyclohexylphosphine with the S-based palladacycle [{Pd(?-OAc)(?(2)-S, C-C6H4CH2SMe)}(2)] gives several products, regardless of stoichiometry, one of which, [Pd(?(1)-OAc)(?(1)-C6H4CH2SMe)(PCy3)(2)], has been characterised crystallographically. Despite this, catalysts formed in situ from di- and tri-alkylphosphines and [{Pd(?-OAc)(?(2)-S, C-C6H4CH2SMe)}(2)] show excellent activity in the Suzuki coupling of a range of deactivated, non-activated and activated aryl chloride substrates.

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More information

Published date: 2004
Keywords: highly efficient catalysts, triarylphosphite complexes, phosphinite complexes, active catalysts, heck reactions, c-c, palladium, ligand, water, coordination

Identifiers

Local EPrints ID: 39102
URI: https://eprints.soton.ac.uk/id/eprint/39102
ISSN: 1477-9226
PURE UUID: e15a003c-05a0-4eb1-bc69-576942a84bc1
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 20 Jun 2006
Last modified: 15 Aug 2019 00:50

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