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trans-bis [1,2-bis(diphenylphosphino)ethane-?P-2,P '] bis [4-(trimethylsilyl)buta-1,3-diynyl] ruthenium(II) and trans-bis [1,2-bis(diphenylphosphino)ethane-?P-2,P '] bis(buta-1,3-diynyl)ruthenium(II)

trans-bis [1,2-bis(diphenylphosphino)ethane-?P-2,P '] bis [4-(trimethylsilyl)buta-1,3-diynyl] ruthenium(II) and trans-bis [1,2-bis(diphenylphosphino)ethane-?P-2,P '] bis(buta-1,3-diynyl)ruthenium(II)
trans-bis [1,2-bis(diphenylphosphino)ethane-?P-2,P '] bis [4-(trimethylsilyl)buta-1,3-diynyl] ruthenium(II) and trans-bis [1,2-bis(diphenylphosphino)ethane-?P-2,P '] bis(buta-1,3-diynyl)ruthenium(II)
The crystal structures of the title compounds, [Ru(C7H9Si)(2)(C26H24P2)(2)] and [Ru(C4H)(2)(C26H24P2)(2)], are described. The metal centre in both complexes has an octahedral coordination geometry, with mutually trans buta-1,3-diynyl ligands forming pseudo-linear ruthenium-centred polyyne chains.
molecular wires, complexes, devices
M215-M217
Anderson, J.N.
a98158f6-b026-4c97-883a-f55a6d3ac61e
Brookes, N.J.
86f48d6b-07ab-4f1f-80b7-cb751e0ca37c
Coe, B.J.
bcf93592-85df-4a69-a1cf-aea0a9152789
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Anderson, J.N.
a98158f6-b026-4c97-883a-f55a6d3ac61e
Brookes, N.J.
86f48d6b-07ab-4f1f-80b7-cb751e0ca37c
Coe, B.J.
bcf93592-85df-4a69-a1cf-aea0a9152789
Coles, S.J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Light, M.E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, M.B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Anderson, J.N., Brookes, N.J., Coe, B.J., Coles, S.J., Light, M.E. and Hursthouse, M.B. (2003) trans-bis [1,2-bis(diphenylphosphino)ethane-?P-2,P '] bis [4-(trimethylsilyl)buta-1,3-diynyl] ruthenium(II) and trans-bis [1,2-bis(diphenylphosphino)ethane-?P-2,P '] bis(buta-1,3-diynyl)ruthenium(II). Acta Crystallographica Section C-Crystal Structure Communications, 59 (6), M215-M217. (doi:10.1107/S0108270103007716).

Record type: Article

Abstract

The crystal structures of the title compounds, [Ru(C7H9Si)(2)(C26H24P2)(2)] and [Ru(C4H)(2)(C26H24P2)(2)], are described. The metal centre in both complexes has an octahedral coordination geometry, with mutually trans buta-1,3-diynyl ligands forming pseudo-linear ruthenium-centred polyyne chains.

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Published date: 2003
Keywords: molecular wires, complexes, devices

Identifiers

Local EPrints ID: 39113
URI: http://eprints.soton.ac.uk/id/eprint/39113
PURE UUID: d49dac2a-292e-4f4f-83bb-8faf9e756e8d
ORCID for S.J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for M.E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 21 Jun 2006
Last modified: 09 Jan 2022 02:59

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Contributors

Author: J.N. Anderson
Author: N.J. Brookes
Author: B.J. Coe
Author: S.J. Coles ORCID iD
Author: M.E. Light ORCID iD
Author: M.B. Hursthouse

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