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Dimerisations of cinnamates using acidic and acidic/oxidative conditions

Dimerisations of cinnamates using acidic and acidic/oxidative conditions
Dimerisations of cinnamates using acidic and acidic/oxidative conditions
It is confirmed that the dimerisation of methyl dialkoxycinnamates in acidic conditions yields trisubstituted indanes. When the reactions are carried out for 1.5 h/0°C in acidic conditions in the presence of DDQ then a variety of lignan types result, two of which represent new classes of lignans.
cinnamates, coupling reactions, acidic-oxidative conditions, novel lignans
0040-4020
7755-7763
Pelter, Andrew
829d43c2-8a6b-49d2-b2de-8864c957b567
Ward, Robert S.
9ccbc3b7-1d93-4c16-a820-e9713d1a3a00
Venkateswarlu, Reveru
7ff9f952-e95c-486a-ae77-05a759796665
Kamakshi, Chakicherla
c84ebdf1-681e-4137-a64f-ac44923c3e0c
Moinuddin, Syed G. A.
d7fd3bba-ee3f-44c7-9a99-3024f7af2ba5
Subhash, Pithani V.
ba226dec-a438-4c11-bf42-4a0de2f3e99f
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Pelter, Andrew
829d43c2-8a6b-49d2-b2de-8864c957b567
Ward, Robert S.
9ccbc3b7-1d93-4c16-a820-e9713d1a3a00
Venkateswarlu, Reveru
7ff9f952-e95c-486a-ae77-05a759796665
Kamakshi, Chakicherla
c84ebdf1-681e-4137-a64f-ac44923c3e0c
Moinuddin, Syed G. A.
d7fd3bba-ee3f-44c7-9a99-3024f7af2ba5
Subhash, Pithani V.
ba226dec-a438-4c11-bf42-4a0de2f3e99f
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161

Pelter, Andrew, Ward, Robert S., Venkateswarlu, Reveru, Kamakshi, Chakicherla, Moinuddin, Syed G. A., Subhash, Pithani V., Hursthouse, Michael B., Coles, Simon J. and Light, Mark E. (2001) Dimerisations of cinnamates using acidic and acidic/oxidative conditions. Tetrahedron, 57 (36), 7755-7763. (doi:10.1016/S0040-4020(01)00742-6).

Record type: Article

Abstract

It is confirmed that the dimerisation of methyl dialkoxycinnamates in acidic conditions yields trisubstituted indanes. When the reactions are carried out for 1.5 h/0°C in acidic conditions in the presence of DDQ then a variety of lignan types result, two of which represent new classes of lignans.

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More information

Published date: 2001
Keywords: cinnamates, coupling reactions, acidic-oxidative conditions, novel lignans

Identifiers

Local EPrints ID: 39120
URI: http://eprints.soton.ac.uk/id/eprint/39120
ISSN: 0040-4020
PURE UUID: 41ebc4b8-8f67-49fb-96aa-75ed2cce07d6
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 21 Jun 2006
Last modified: 20 Jul 2019 01:10

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Contributors

Author: Andrew Pelter
Author: Robert S. Ward
Author: Reveru Venkateswarlu
Author: Chakicherla Kamakshi
Author: Syed G. A. Moinuddin
Author: Pithani V. Subhash
Author: Simon J. Coles ORCID iD
Author: Mark E. Light ORCID iD

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