Synthesis of dinuclear complexes of rhenium(I) as potential metallomesogens
Synthesis of dinuclear complexes of rhenium(I) as potential metallomesogens
Seven anisotropic diimines and their corresponding dinuclear complexes of rhenium(I) have been synthesized. The crystal and molecular structures of one of the dimines and two of the complexes were determined. In common with related imine ligands which have been synthesized previously, the new diimines were mesomorphic showing smectic C and nematic phases and, in some cases, smectic I and crystal J phases. However, none of the orthometallated, dinuclear complexes showed any liquid crystal phases.
manganese(i)
1437-1445
Guillevic, M. A.
f614158d-65ed-41e6-9b0b-0d93a5c03ae1
Light, M. E.
5f2f6119-008d-4681-8ea0-e32559c94ddd
Coles, S. J.
503a9d9c-0380-4fcd-ad31-cd329255c08e
Gelbrich, T.
6874d813-bf11-4950-b322-dfe77c533f41
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Bruce, D. W.
7ec20cab-29a4-48be-aa0d-4935312013ef
2000
Guillevic, M. A.
f614158d-65ed-41e6-9b0b-0d93a5c03ae1
Light, M. E.
5f2f6119-008d-4681-8ea0-e32559c94ddd
Coles, S. J.
503a9d9c-0380-4fcd-ad31-cd329255c08e
Gelbrich, T.
6874d813-bf11-4950-b322-dfe77c533f41
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Bruce, D. W.
7ec20cab-29a4-48be-aa0d-4935312013ef
Guillevic, M. A., Light, M. E., Coles, S. J., Gelbrich, T., Hursthouse, M. B. and Bruce, D. W.
(2000)
Synthesis of dinuclear complexes of rhenium(I) as potential metallomesogens.
Journal of the Chemical Society, Dalton Transactions, 9, .
Abstract
Seven anisotropic diimines and their corresponding dinuclear complexes of rhenium(I) have been synthesized. The crystal and molecular structures of one of the dimines and two of the complexes were determined. In common with related imine ligands which have been synthesized previously, the new diimines were mesomorphic showing smectic C and nematic phases and, in some cases, smectic I and crystal J phases. However, none of the orthometallated, dinuclear complexes showed any liquid crystal phases.
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Published date: 2000
Keywords:
manganese(i)
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Local EPrints ID: 39127
URI: http://eprints.soton.ac.uk/id/eprint/39127
PURE UUID: 4ace16a3-9d0a-40f0-8d68-6d11404a49ae
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Date deposited: 17 Jul 2006
Last modified: 08 Jan 2022 01:06
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Contributors
Author:
M. A. Guillevic
Author:
M. E. Light
Author:
S. J. Coles
Author:
T. Gelbrich
Author:
D. W. Bruce
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