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Synthesis of dinuclear complexes of rhenium(I) as potential metallomesogens

Synthesis of dinuclear complexes of rhenium(I) as potential metallomesogens
Synthesis of dinuclear complexes of rhenium(I) as potential metallomesogens
Seven anisotropic diimines and their corresponding dinuclear complexes of rhenium(I) have been synthesized. The crystal and molecular structures of one of the dimines and two of the complexes were determined. In common with related imine ligands which have been synthesized previously, the new diimines were mesomorphic showing smectic C and nematic phases and, in some cases, smectic I and crystal J phases. However, none of the orthometallated, dinuclear complexes showed any liquid crystal phases.
manganese(i)
1437-1445
Guillevic, M. A.
f614158d-65ed-41e6-9b0b-0d93a5c03ae1
Light, M. E.
5f2f6119-008d-4681-8ea0-e32559c94ddd
Coles, S. J.
503a9d9c-0380-4fcd-ad31-cd329255c08e
Gelbrich, T.
6874d813-bf11-4950-b322-dfe77c533f41
Hursthouse, M. B.
276e7125-0773-43f6-97e3-77106e9b6e8f
Bruce, D. W.
7ec20cab-29a4-48be-aa0d-4935312013ef
Guillevic, M. A.
f614158d-65ed-41e6-9b0b-0d93a5c03ae1
Light, M. E.
5f2f6119-008d-4681-8ea0-e32559c94ddd
Coles, S. J.
503a9d9c-0380-4fcd-ad31-cd329255c08e
Gelbrich, T.
6874d813-bf11-4950-b322-dfe77c533f41
Hursthouse, M. B.
276e7125-0773-43f6-97e3-77106e9b6e8f
Bruce, D. W.
7ec20cab-29a4-48be-aa0d-4935312013ef

Guillevic, M. A., Light, M. E., Coles, S. J., Gelbrich, T., Hursthouse, M. B. and Bruce, D. W. (2000) Synthesis of dinuclear complexes of rhenium(I) as potential metallomesogens. Journal of the Chemical Society, Dalton Transactions, 9, 1437-1445.

Record type: Article

Abstract

Seven anisotropic diimines and their corresponding dinuclear complexes of rhenium(I) have been synthesized. The crystal and molecular structures of one of the dimines and two of the complexes were determined. In common with related imine ligands which have been synthesized previously, the new diimines were mesomorphic showing smectic C and nematic phases and, in some cases, smectic I and crystal J phases. However, none of the orthometallated, dinuclear complexes showed any liquid crystal phases.

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More information

Published date: 2000
Keywords: manganese(i)

Identifiers

Local EPrints ID: 39127
URI: http://eprints.soton.ac.uk/id/eprint/39127
PURE UUID: 4ace16a3-9d0a-40f0-8d68-6d11404a49ae

Catalogue record

Date deposited: 17 Jul 2006
Last modified: 15 Jul 2019 19:01

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