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Utilisation of gold nanoparticles on amine-functionalised UiO-66 (NH2-UiO-66) nanocrystals for selective tandem catalytic reactions

Utilisation of gold nanoparticles on amine-functionalised UiO-66 (NH2-UiO-66) nanocrystals for selective tandem catalytic reactions
Utilisation of gold nanoparticles on amine-functionalised UiO-66 (NH2-UiO-66) nanocrystals for selective tandem catalytic reactions
Colloidal deposition of gold nanoparticles (Au NPs) onto NH2-UiO-66 nanocrystals has been demonstrated with the resulting hybrid catalyst proving robust and versatile for one-pot, heterogeneous conversions involving the selective oxidation of primary alcohols in tandem with Knoevenagel condensation reactions. Within these systems, structure-property correlations have been established to confirm that the active sites for the oxidation and condensation reactions are intrinsically correlated to the Au NPs and pendant amine groups respectively.
1359-7345
6557-6560
Hinde, Christopher
08da9ba4-06f6-433c-a6f9-269441ffa557
Webb, William
fb2b9d49-23f1-4645-aaf5-f92dd5f6bdad
Chew, Benny Kia Jia
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Tan, Hui Ru
2ba81f28-8e77-48b3-9b46-1f1978642b48
Zhang, Wen-Hua
639e1bd7-72bd-4dfa-a56a-ea24a68c0a12
Hor, Andy
0ebe0305-1733-4397-8925-9c2eca46724a
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Hinde, Christopher
08da9ba4-06f6-433c-a6f9-269441ffa557
Webb, William
fb2b9d49-23f1-4645-aaf5-f92dd5f6bdad
Chew, Benny Kia Jia
7aecfd3c-27ec-4613-ad1b-cd18ed31ac2a
Tan, Hui Ru
2ba81f28-8e77-48b3-9b46-1f1978642b48
Zhang, Wen-Hua
639e1bd7-72bd-4dfa-a56a-ea24a68c0a12
Hor, Andy
0ebe0305-1733-4397-8925-9c2eca46724a
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b

Hinde, Christopher, Webb, William, Chew, Benny Kia Jia, Tan, Hui Ru, Zhang, Wen-Hua, Hor, Andy and Raja, Robert (2016) Utilisation of gold nanoparticles on amine-functionalised UiO-66 (NH2-UiO-66) nanocrystals for selective tandem catalytic reactions. Chemical Communications, 2016 (39), 6557-6560. (doi:10.1039/C6CC02169G).

Record type: Article

Abstract

Colloidal deposition of gold nanoparticles (Au NPs) onto NH2-UiO-66 nanocrystals has been demonstrated with the resulting hybrid catalyst proving robust and versatile for one-pot, heterogeneous conversions involving the selective oxidation of primary alcohols in tandem with Knoevenagel condensation reactions. Within these systems, structure-property correlations have been established to confirm that the active sites for the oxidation and condensation reactions are intrinsically correlated to the Au NPs and pendant amine groups respectively.

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Accepted/In Press date: 11 April 2016
e-pub ahead of print date: 11 April 2016
Published date: 14 May 2016
Organisations: Organic Chemistry: SCF

Identifiers

Local EPrints ID: 392808
URI: http://eprints.soton.ac.uk/id/eprint/392808
DOI: doi:10.1039/C6CC02169G
ISSN: 1359-7345
PURE UUID: c6d72da0-de49-46aa-a05f-662b7dc501a6
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 18 Apr 2016 09:23
Last modified: 15 Mar 2024 05:30

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Contributors

Author: Christopher Hinde
Author: William Webb
Author: Benny Kia Jia Chew
Author: Hui Ru Tan
Author: Wen-Hua Zhang
Author: Andy Hor
Author: Robert Raja ORCID iD

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