Nava, J.L., Sosa, E., Carreno, G., Ponce de Leon Albarran, C.A. and Oropeza, M.T.
Modelling of the concentration–time relationship based on global
diffusion-charge transfer parameters in a flow-by
reactor with a 3D electrode
Electrochimica Acta, 51, (20), . (doi:10.1016/j.electacta.2005.12.002).
Full text not available from this repository.
A concentration versus time relationship model based on the isothermal diffusion-charge transfer mechanism was developed for a flow-by reactor with a three-dimensional (3D) reticulated vitreous carbon (RVC) electrode. The relationship was based on the effectiveness factor (?) which lead to the simulation of the concentration decay at different electrode polarisation conditions, i.e.?0.1,?0.3 and?0.59V versus SCE; the charge transfer process was used for the former and mix and a mass transport control was used for the latter. Charge transfer and mass transport parameters were estimated from experimental data using Electrochemical Impedance Spectroscopy (EIS) and Linear Voltammetry (LV) techniques, respectively.
|Digital Object Identifier (DOI):
||concentration–time relationship, copper, diffusion-charge transfer mechanism, effectiveness factor, flow-by reactor, mass transport, RVC, 3D electrode
||Engineering Mats & Surface Engineerg Gp
|20 September 2005||Submitted|
|25 May 2006||Published|
||27 Jun 2006
||16 Apr 2017 21:56
|Further Information:||Google Scholar|
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