Spectroscopic and computational insights on catalytic synergy in bimetallic aluminophosphate catalysts
Spectroscopic and computational insights on catalytic synergy in bimetallic aluminophosphate catalysts
A combined electronic structure computational and X-ray absorption spectroscopy study was used to investigate the nature of the active sites responsible for catalytic synergy in Co-Ti bimetallic nanoporous frameworks. Probing the nature of the molecular species at the atomic level has led to the identification of a unique Co-O-Ti bond, which serves as the loci for the superior performance of the bimetallic catalyst, when compared with its analogous monometallic counterpart. The structural and spectroscopic features associated with this active site have been characterized and contrasted, with a view to affording structure property relationships, in the wider context of designing sustainable catalytic oxidations with porous solids.
8534-8540
Potter, Matthew
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Paterson, A. James
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Mishra, Bhoopesh
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Kelly, Shelly D.
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Bare, Simon R.
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Corà, Furio
42617dab-0825-45cd-9a00-9e250cc8777b
Levy, Alan B.
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Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
8 July 2015
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Paterson, A. James
1d034012-e93a-4bb8-bcc0-ca561e9597ad
Mishra, Bhoopesh
11acd041-ec6a-461e-a4a0-20e5f8859bfe
Kelly, Shelly D.
4ee034cc-6c6c-4ba1-a13e-debdf7166923
Bare, Simon R.
74aea019-9076-4148-ab37-21d3197dc393
Corà, Furio
42617dab-0825-45cd-9a00-9e250cc8777b
Levy, Alan B.
b6f54b52-0292-413b-a36f-d056e4d1204f
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Potter, Matthew, Paterson, A. James, Mishra, Bhoopesh, Kelly, Shelly D., Bare, Simon R., Corà, Furio, Levy, Alan B. and Raja, Robert
(2015)
Spectroscopic and computational insights on catalytic synergy in bimetallic aluminophosphate catalysts.
Journal of the American Chemical Society, 137 (26), .
(doi:10.1021/jacs.5b03734).
(PMID:26076192)
Abstract
A combined electronic structure computational and X-ray absorption spectroscopy study was used to investigate the nature of the active sites responsible for catalytic synergy in Co-Ti bimetallic nanoporous frameworks. Probing the nature of the molecular species at the atomic level has led to the identification of a unique Co-O-Ti bond, which serves as the loci for the superior performance of the bimetallic catalyst, when compared with its analogous monometallic counterpart. The structural and spectroscopic features associated with this active site have been characterized and contrasted, with a view to affording structure property relationships, in the wider context of designing sustainable catalytic oxidations with porous solids.
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e-pub ahead of print date: 15 June 2015
Published date: 8 July 2015
Organisations:
Organic Chemistry: SCF
Identifiers
Local EPrints ID: 395575
URI: http://eprints.soton.ac.uk/id/eprint/395575
ISSN: 0002-7863
PURE UUID: c94684c6-fcc3-41ef-b9f3-8656e592dbc8
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Date deposited: 01 Jun 2016 13:54
Last modified: 15 Mar 2024 03:26
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Contributors
Author:
A. James Paterson
Author:
Bhoopesh Mishra
Author:
Shelly D. Kelly
Author:
Simon R. Bare
Author:
Furio Corà
Author:
Alan B. Levy
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