The University of Southampton
×
Filter your search:
University of Southampton Institutional Repository

Iterative synthesis of oligo[n]rotaxanes in excellent yield

Iterative synthesis of oligo[n]rotaxanes in excellent yield
Iterative synthesis of oligo[n]rotaxanes in excellent yield
We present an operationally simple iterative coupling strategy for the synthesis of oligomeric homo- and hetero-[n]rotaxanes with precise control over the position of each macrocycle. The exceptional yield of the AT-CuAAC reaction, combined with optimized conditions that allow the rapid synthesis of the target oligomers, opens the door to the study of precision-engineered oligomeric interlocked molecules.
0002-7863
16329-16336
Lewis, James E.M.
42b46a03-a7ca-4d3a-96e5-a5c962fc9573
Winn, Joby
5f38d7c8-e656-4191-85c5-1323197b0bdd
Cera, Luca
71d8e90f-7651-4ccd-bc15-d87b930b3198
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Lewis, James E.M.
42b46a03-a7ca-4d3a-96e5-a5c962fc9573
Winn, Joby
5f38d7c8-e656-4191-85c5-1323197b0bdd
Cera, Luca
71d8e90f-7651-4ccd-bc15-d87b930b3198
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937

Lewis, James E.M., Winn, Joby, Cera, Luca and Goldup, Stephen M. (2016) Iterative synthesis of oligo[n]rotaxanes in excellent yield. Journal of the American Chemical Society, 138 (50), 16329-16336. (doi:10.1021/jacs.6b08958).

Record type: Article

Abstract

We present an operationally simple iterative coupling strategy for the synthesis of oligomeric homo- and hetero-[n]rotaxanes with precise control over the position of each macrocycle. The exceptional yield of the AT-CuAAC reaction, combined with optimized conditions that allow the rapid synthesis of the target oligomers, opens the door to the study of precision-engineered oligomeric interlocked molecules.

Text
rvsd SG MS Lewis Oligorotaxanes JACS.pdf - Accepted Manuscript
Available under License University of Southampton Accepted Manuscript Licence.
Download (2MB)

More information

Accepted/In Press date: 4 October 2016
e-pub ahead of print date: 18 October 2016
Published date: 21 December 2016
Related URLs:
Organisations: Chemistry
Learn more about Chemistry research

Identifiers

Local EPrints ID: 401225
URI: http://eprints.soton.ac.uk/id/eprint/401225
DOI: doi:10.1021/jacs.6b08958
ISSN: 0002-7863
PURE UUID: 2f6d91b3-44a4-4e5e-858b-52efce2ca698
ORCID for Stephen M. Goldup: ORCID iD orcid.org/0000-0003-3781-0464

Catalogue record

Date deposited: 11 Oct 2016 10:55
Last modified: 15 Mar 2024 05:57

Export record

Altmetrics

Contributors

Author: James E.M. Lewis
Author: Joby Winn
Author: Luca Cera
Author: Stephen M. Goldup ORCID iD

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information
Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×