Influence of dopant substitution mechanism on catalytic properties within hierarchical architectures
Influence of dopant substitution mechanism on catalytic properties within hierarchical architectures
A range of hierarchically porous (HP) AlPO-5 catalysts, with isomorphously substituted transition metal ions, have been synthesized using an organosilane as a soft template. By employing a range of structural and spectroscopic characterization protocols, the properties of the dopant-substituted species within the HP architectures have been carefully evaluated. The resulting nature of the active site is shown to have a direct impact on the ensuing catalytic properties in the liquid-phase Beckmann rearrangement of cyclic ketones.
1-15
Newland, Stephanie
dc459841-89d5-4b96-b862-526b03f30e03
Sinkler, Wharton
20c463cb-85e9-4751-a092-9f0155f72cf7
Mezza, Thomas
c81e4984-d885-4a18-a1b5-64c5d5ca275e
Bare, Simon R.
74aea019-9076-4148-ab37-21d3197dc393
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Newland, Stephanie
dc459841-89d5-4b96-b862-526b03f30e03
Sinkler, Wharton
20c463cb-85e9-4751-a092-9f0155f72cf7
Mezza, Thomas
c81e4984-d885-4a18-a1b5-64c5d5ca275e
Bare, Simon R.
74aea019-9076-4148-ab37-21d3197dc393
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Newland, Stephanie, Sinkler, Wharton, Mezza, Thomas, Bare, Simon R. and Raja, Robert
(2016)
Influence of dopant substitution mechanism on catalytic properties within hierarchical architectures.
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 472 (2191), .
(doi:10.1098/rspa.2016.0095).
Abstract
A range of hierarchically porous (HP) AlPO-5 catalysts, with isomorphously substituted transition metal ions, have been synthesized using an organosilane as a soft template. By employing a range of structural and spectroscopic characterization protocols, the properties of the dopant-substituted species within the HP architectures have been carefully evaluated. The resulting nature of the active site is shown to have a direct impact on the ensuing catalytic properties in the liquid-phase Beckmann rearrangement of cyclic ketones.
Text
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- Accepted Manuscript
More information
Accepted/In Press date: 13 June 2016
e-pub ahead of print date: 13 July 2016
Organisations:
Organic Chemistry: SCF
Identifiers
Local EPrints ID: 401740
URI: http://eprints.soton.ac.uk/id/eprint/401740
ISSN: 1364-5021
PURE UUID: d7ad6783-f459-4571-86d5-53a6ff4fd4fc
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Date deposited: 20 Oct 2016 13:51
Last modified: 15 Mar 2024 05:59
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Contributors
Author:
Stephanie Newland
Author:
Wharton Sinkler
Author:
Thomas Mezza
Author:
Simon R. Bare
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