Constructing chiral MOFs by functionalizing 4,2':6',4"-terpyridine with long-chain alkoxy domains: rare examples of neb nets
Constructing chiral MOFs by functionalizing 4,2':6',4"-terpyridine with long-chain alkoxy domains: rare examples of neb nets
Reactions of 4'-(4-nalkyloxyphenyl)-4,2':6',4"-terpyridines (alkyl = hexyl or nonyl) with Co(NCS)2 lead to three structurally characterized chiral 3D assemblies which adopt rare neb topologies. For the nhexyl-functionalized ligands, both enantiomorphic lattices of the neb nets (crystallizing in the tetragonal space groups P41212 and P43212, respectively) are presented.
4704-4707
Klein, Y. Maximilian
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Prescimone, Alessandro
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Pitak, Mateusz
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Coles, Simon
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Constable, Edwin C.
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Housecroft, Catherine E.
b63e2e1e-5ab0-4c20-858f-102cd71e5128
7 July 2016
Klein, Y. Maximilian
aa1bec65-f1ef-435f-9aea-ddf801cffda6
Prescimone, Alessandro
9daa1cc4-3a2a-4288-9ec5-167e3fd15e92
Pitak, Mateusz
eeb6a00f-2291-4376-830f-d30dfd607ed1
Coles, Simon
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Constable, Edwin C.
d7da4205-ec75-47b5-a666-9ce90618069b
Housecroft, Catherine E.
b63e2e1e-5ab0-4c20-858f-102cd71e5128
Klein, Y. Maximilian, Prescimone, Alessandro, Pitak, Mateusz, Coles, Simon, Constable, Edwin C. and Housecroft, Catherine E.
(2016)
Constructing chiral MOFs by functionalizing 4,2':6',4"-terpyridine with long-chain alkoxy domains: rare examples of neb nets.
CrystEngComm, 18 (25), .
(doi:10.1039/C6CE00939E).
Abstract
Reactions of 4'-(4-nalkyloxyphenyl)-4,2':6',4"-terpyridines (alkyl = hexyl or nonyl) with Co(NCS)2 lead to three structurally characterized chiral 3D assemblies which adopt rare neb topologies. For the nhexyl-functionalized ligands, both enantiomorphic lattices of the neb nets (crystallizing in the tetragonal space groups P41212 and P43212, respectively) are presented.
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c6ce00939e.pdf
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Accepted/In Press date: 16 May 2016
e-pub ahead of print date: 24 May 2016
Published date: 7 July 2016
Organisations:
Characterisation and Analytics, Organic Chemistry: SCF
Identifiers
Local EPrints ID: 402132
URI: http://eprints.soton.ac.uk/id/eprint/402132
ISSN: 1466-8033
PURE UUID: 564fa833-35d4-4119-b720-e93de710320a
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Date deposited: 01 Nov 2016 16:58
Last modified: 16 Mar 2024 03:05
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Contributors
Author:
Y. Maximilian Klein
Author:
Alessandro Prescimone
Author:
Mateusz Pitak
Author:
Edwin C. Constable
Author:
Catherine E. Housecroft
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