An extended channel length microflow electrolysis cell for convenient laboratory synthesis
An extended channel length microflow electrolysis cell for convenient laboratory synthesis
A spiral, extended channel length microflow cell designed for routine and convenient application in an organic synthesis laboratory is described. The performance of the cell is demonstrated using two syntheses and it is shown that high selectivities and high conversions in a single pass can be achieved as well as the formation of products at a rate of up to 25mmol/h (~3 g/h). The cell is also well suited to carrying out the optimisation of reaction conditions with electrolyses completed on a timescale of minutes.
63-66
Green, Robert
b94d81d2-c00e-4fcb-bbcd-2998250be0e9
Brown, Richard
21ce697a-7c3a-480e-919f-429a3d8550f5
Pletcher, Derek
f22ebe69-b859-4a89-80b0-9e190e6f8f30
Harji, Bashir
94c4a1a5-9ece-4968-9df2-ac63ca322c62
December 2016
Green, Robert
b94d81d2-c00e-4fcb-bbcd-2998250be0e9
Brown, Richard
21ce697a-7c3a-480e-919f-429a3d8550f5
Pletcher, Derek
f22ebe69-b859-4a89-80b0-9e190e6f8f30
Harji, Bashir
94c4a1a5-9ece-4968-9df2-ac63ca322c62
Green, Robert, Brown, Richard, Pletcher, Derek and Harji, Bashir
(2016)
An extended channel length microflow electrolysis cell for convenient laboratory synthesis.
Electrochemistry Communications, 73, .
(doi:10.1016/j.elecom.2016.11.004).
Abstract
A spiral, extended channel length microflow cell designed for routine and convenient application in an organic synthesis laboratory is described. The performance of the cell is demonstrated using two syntheses and it is shown that high selectivities and high conversions in a single pass can be achieved as well as the formation of products at a rate of up to 25mmol/h (~3 g/h). The cell is also well suited to carrying out the optimisation of reaction conditions with electrolyses completed on a timescale of minutes.
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An extended channel length microflow electrolysis cell for convenient laboratory synthesis.pdf
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More information
Submitted date: 14 October 2016
Accepted/In Press date: 4 November 2016
e-pub ahead of print date: 5 November 2016
Published date: December 2016
Additional Information:
Funded by EPSRC: Factory in a Fumehood: Reagentless Flow Reactors as Enabling Techniques for Manufacture (EP/L003325/1)
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 403052
URI: http://eprints.soton.ac.uk/id/eprint/403052
ISSN: 1388-2481
PURE UUID: c408a9e9-9247-4856-bee2-854df4153943
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Date deposited: 22 Nov 2016 16:28
Last modified: 16 Mar 2024 02:54
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Contributors
Author:
Robert Green
Author:
Bashir Harji
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