Synthesis, characterization, magnetic and catalytic properties of a ladder-shaped MnII coordination polymer
Synthesis, characterization, magnetic and catalytic properties of a ladder-shaped MnII coordination polymer
[Mn(LH)(H2O)]n {1, where LH2– is the dianion of N-(4-carboxybenzyl)iminodiacetic acid} has been synthesized and its crystal structure has been determined. The crystal of 1 is built from 1D polymeric ladder-shaped chains that extend to a 3D supramolecular architecture through H-bonds. The compound was characterized with spectroscopic and physicochemical techniques. Variable-temperature magnetic data suggest that there are weak antiferromagnetic interactions. Compound 1 has been evaluated as a heterogeneous oxidation catalyst. It catalyzes alkene epoxidation selectively in relatively high yields.
3638-3644
Lymperopoulou, Smaragda
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Papastergiou, Maria
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Louloudi, Maria
7587b089-7563-49da-838b-8e5a2cacd5e7
Raptopoulou, Catherine P.
9bd1f70c-2922-4e14-a86b-5a23174f5b97
Psycharis, Vassilis
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Milios, Constantinos J.
516ed916-50ec-4b55-a361-530efa293373
Plakatouras, John C.
60eeb53f-491a-44e9-ac12-33b61abb2635
August 2014
Lymperopoulou, Smaragda
8a5b1800-8ead-44f6-91ce-5ec6e0f12abd
Papastergiou, Maria
eab2e10c-8d0c-4d39-98a9-b54b112c0e9e
Louloudi, Maria
7587b089-7563-49da-838b-8e5a2cacd5e7
Raptopoulou, Catherine P.
9bd1f70c-2922-4e14-a86b-5a23174f5b97
Psycharis, Vassilis
09079574-89d2-4571-b359-6b7c93828cba
Milios, Constantinos J.
516ed916-50ec-4b55-a361-530efa293373
Plakatouras, John C.
60eeb53f-491a-44e9-ac12-33b61abb2635
Lymperopoulou, Smaragda, Papastergiou, Maria, Louloudi, Maria, Raptopoulou, Catherine P., Psycharis, Vassilis, Milios, Constantinos J. and Plakatouras, John C.
(2014)
Synthesis, characterization, magnetic and catalytic properties of a ladder-shaped MnII coordination polymer.
European Journal of Inorganic Chemistry, 2014 (23), .
(doi:10.1002/ejic.201402419).
Abstract
[Mn(LH)(H2O)]n {1, where LH2– is the dianion of N-(4-carboxybenzyl)iminodiacetic acid} has been synthesized and its crystal structure has been determined. The crystal of 1 is built from 1D polymeric ladder-shaped chains that extend to a 3D supramolecular architecture through H-bonds. The compound was characterized with spectroscopic and physicochemical techniques. Variable-temperature magnetic data suggest that there are weak antiferromagnetic interactions. Compound 1 has been evaluated as a heterogeneous oxidation catalyst. It catalyzes alkene epoxidation selectively in relatively high yields.
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e-pub ahead of print date: 15 July 2014
Published date: August 2014
Organisations:
Organic Chemistry: SCF
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Local EPrints ID: 403242
URI: http://eprints.soton.ac.uk/id/eprint/403242
ISSN: 1434-1948
PURE UUID: 098078bf-60da-4b22-8478-0603438eec07
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Date deposited: 29 Nov 2016 10:06
Last modified: 15 Mar 2024 03:37
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Author:
Smaragda Lymperopoulou
Author:
Maria Papastergiou
Author:
Maria Louloudi
Author:
Catherine P. Raptopoulou
Author:
Vassilis Psycharis
Author:
Constantinos J. Milios
Author:
John C. Plakatouras
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