Influence of the metal salt on the self-assembly of isophthaloylbis-B-alanine and Cu(II) ion
Influence of the metal salt on the self-assembly of isophthaloylbis-B-alanine and Cu(II) ion
The initial employment of the new pseudopeptidic ligand isophthaloylbis-?-alanine (H2IBbA, H2L) with CuII ion affords a one dimensional (1D) [Cu2L2(H2O)(CH3OH)]·2H2O·CH3OH (1) and a two dimensional (2D) [Cu2L2(H2O)4]·6H2O (2) compound, respectively, illustrating the important influence of the metal salt and the solvent system used in determining the motif of the final product. Infrared spectroscopy, thermal, adsorption and theoretical studies of these compounds are also discussed.
313-321
Lymperopoulou, Smaragda
8a5b1800-8ead-44f6-91ce-5ec6e0f12abd
Dokorou, Vassiliki N.
c49c34c2-aac7-4329-820e-2cf996ea0002
Tsipis, Athanassios C.
16b23a31-6d5d-4031-9502-bc11de5fc47d
Weidler, Peter G.
57d64c93-092f-4d34-ad14-42d0e6089e48
Plakatouras, John C.
60eeb53f-491a-44e9-ac12-33b61abb2635
Powell, Annie K.
84c3aa9f-b469-489c-a4d7-264c4ec39e44
Kostakis, George E.
dd72c724-c82e-4891-aa68-ccdb42cc6cb8
29 March 2015
Lymperopoulou, Smaragda
8a5b1800-8ead-44f6-91ce-5ec6e0f12abd
Dokorou, Vassiliki N.
c49c34c2-aac7-4329-820e-2cf996ea0002
Tsipis, Athanassios C.
16b23a31-6d5d-4031-9502-bc11de5fc47d
Weidler, Peter G.
57d64c93-092f-4d34-ad14-42d0e6089e48
Plakatouras, John C.
60eeb53f-491a-44e9-ac12-33b61abb2635
Powell, Annie K.
84c3aa9f-b469-489c-a4d7-264c4ec39e44
Kostakis, George E.
dd72c724-c82e-4891-aa68-ccdb42cc6cb8
Lymperopoulou, Smaragda, Dokorou, Vassiliki N., Tsipis, Athanassios C., Weidler, Peter G., Plakatouras, John C., Powell, Annie K. and Kostakis, George E.
(2015)
Influence of the metal salt on the self-assembly of isophthaloylbis-B-alanine and Cu(II) ion.
Polyhedron, 89, .
(doi:10.1016/j.poly.2015.01.023).
Abstract
The initial employment of the new pseudopeptidic ligand isophthaloylbis-?-alanine (H2IBbA, H2L) with CuII ion affords a one dimensional (1D) [Cu2L2(H2O)(CH3OH)]·2H2O·CH3OH (1) and a two dimensional (2D) [Cu2L2(H2O)4]·6H2O (2) compound, respectively, illustrating the important influence of the metal salt and the solvent system used in determining the motif of the final product. Infrared spectroscopy, thermal, adsorption and theoretical studies of these compounds are also discussed.
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Accepted/In Press date: 23 January 2015
e-pub ahead of print date: 3 February 2015
Published date: 29 March 2015
Organisations:
Organic Chemistry: SCF
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Local EPrints ID: 403244
URI: http://eprints.soton.ac.uk/id/eprint/403244
ISSN: 0277-5387
PURE UUID: 3aab6b7c-dd4d-4bdd-9a51-bc74b1914e00
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Date deposited: 29 Nov 2016 10:17
Last modified: 15 Mar 2024 03:37
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Author:
Smaragda Lymperopoulou
Author:
Vassiliki N. Dokorou
Author:
Athanassios C. Tsipis
Author:
Peter G. Weidler
Author:
John C. Plakatouras
Author:
Annie K. Powell
Author:
George E. Kostakis
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