Tetranuclear Zn2Ln2 coordination clusters as catalysts in the Petasis borono-Mannich multicomponent reaction
Tetranuclear Zn2Ln2 coordination clusters as catalysts in the Petasis borono-Mannich multicomponent reaction
We report herein for the first time the efficiency of heteronuclear Zn/Ln coordination clusters (CCs) as catalysts for the multicomponent Mannich-type condensation that involves amines, aldehydes and boronic acids, known as the Petasis borono-Mannich (RBR) reaction. The reaction proceeds in very good to excellent yields (84–98%, 17 products) at room temperature with catalyst loadings as low as 1.0 mol%.
79180-79184
Kumar, Prashant
5e332e6f-0450-48c9-9fce-4c663452b8d8
Griffiths, Kieran
91984c79-162c-4653-8521-60b3e76764f2
Lymperopoulou, Smaragda
8a5b1800-8ead-44f6-91ce-5ec6e0f12abd
Kostakis, George E.
dd72c724-c82e-4891-aa68-ccdb42cc6cb8
Kumar, Prashant
5e332e6f-0450-48c9-9fce-4c663452b8d8
Griffiths, Kieran
91984c79-162c-4653-8521-60b3e76764f2
Lymperopoulou, Smaragda
8a5b1800-8ead-44f6-91ce-5ec6e0f12abd
Kostakis, George E.
dd72c724-c82e-4891-aa68-ccdb42cc6cb8
Kumar, Prashant, Griffiths, Kieran, Lymperopoulou, Smaragda and Kostakis, George E.
(2016)
Tetranuclear Zn2Ln2 coordination clusters as catalysts in the Petasis borono-Mannich multicomponent reaction.
RSC Advances, 6 (82), .
(doi:10.1039/C6RA17209A).
Abstract
We report herein for the first time the efficiency of heteronuclear Zn/Ln coordination clusters (CCs) as catalysts for the multicomponent Mannich-type condensation that involves amines, aldehydes and boronic acids, known as the Petasis borono-Mannich (RBR) reaction. The reaction proceeds in very good to excellent yields (84–98%, 17 products) at room temperature with catalyst loadings as low as 1.0 mol%.
This record has no associated files available for download.
More information
Accepted/In Press date: 10 August 2016
e-pub ahead of print date: 15 August 2016
Organisations:
Organic Chemistry: SCF
Identifiers
Local EPrints ID: 403245
URI: http://eprints.soton.ac.uk/id/eprint/403245
ISSN: 2046-2069
PURE UUID: d349fb31-3ea9-4cff-a50f-7112f2c8814d
Catalogue record
Date deposited: 29 Nov 2016 10:20
Last modified: 15 Mar 2024 03:37
Export record
Altmetrics
Contributors
Author:
Prashant Kumar
Author:
Kieran Griffiths
Author:
Smaragda Lymperopoulou
Author:
George E. Kostakis
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics