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Properties and emerging applications of mechanically interlocked ligands

Properties and emerging applications of mechanically interlocked ligands
Properties and emerging applications of mechanically interlocked ligands
Mechanically interlocked molecules have a long and rich history as ligands thanks to the key role coordination chemistry has played in the development of high yielding passive template syntheses of rotaxanes and catenanes. In this Feature Article, we highlight the effect of the mechanical bond on the properties of metal ions bound within the sterically hindered environment of the macrocycle cavity, and discuss the emerging applications of interlocked ligands in catalysis, sensing and supramolecular materials.
1359-7345
298-312
Lewis, James E.M.
42b46a03-a7ca-4d3a-96e5-a5c962fc9573
Galli, Marzia
5bfc8a21-05e5-4f29-a573-4fa4d7938f7f
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Lewis, James E.M.
42b46a03-a7ca-4d3a-96e5-a5c962fc9573
Galli, Marzia
5bfc8a21-05e5-4f29-a573-4fa4d7938f7f
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937

Lewis, James E.M., Galli, Marzia and Goldup, Stephen M. (2016) Properties and emerging applications of mechanically interlocked ligands. [in special issue: Host–guest chemistry] Chemical Communications, 298-312. (doi:10.1039/C6CC07377H).

Record type: Article

Abstract

Mechanically interlocked molecules have a long and rich history as ligands thanks to the key role coordination chemistry has played in the development of high yielding passive template syntheses of rotaxanes and catenanes. In this Feature Article, we highlight the effect of the mechanical bond on the properties of metal ions bound within the sterically hindered environment of the macrocycle cavity, and discuss the emerging applications of interlocked ligands in catalysis, sensing and supramolecular materials.

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Accepted/In Press date: 27 October 2016
e-pub ahead of print date: 7 November 2016
Organisations: Chemistry

Identifiers

Local EPrints ID: 403502
URI: http://eprints.soton.ac.uk/id/eprint/403502
ISSN: 1359-7345
PURE UUID: af99ceb9-a58f-4686-b48e-109675c2a7ee
ORCID for Stephen M. Goldup: ORCID iD orcid.org/0000-0003-3781-0464

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Date deposited: 02 Dec 2016 11:00
Last modified: 15 Sep 2021 05:04

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