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Chemical sensors for in situ data collection in the cryosphere

Chemical sensors for in situ data collection in the cryosphere
Chemical sensors for in situ data collection in the cryosphere
Glaciers and ice sheets are recognised as important components of global biogeochemical cycles. Chemical sensors have great potential for in situ monitoring in the cryosphere and are available for many analytes of interest, but they are frequently unsuitable for deployment since meltwaters are cold, turbid, experience freeze-thaw cycles and display low ionic strength and concentrations of target analytes. Here, we review in situ chemical sensors currently available for measurement of biogeochemically important analytes and assess their suitability for deployment. These include standard parameters such as dissolved oxygen and pH, along with macronutrients (nitrate/nitrite and phosphate), micronutrients (iron and manganese) and biogenic gases (methane). Where no commercial alternatives are available, we discuss sensors currently in development, and their applicability to these extreme environments. The information presented has great relevance for future science in polar environments, and for the ultimate goal of obtaining in situ data from extreme, inaccessible subglacial environments.
Cryosphere, Chemical sensors, Glacial meltwater, Oxygen, pH, Methane, Nitrate, Phosphate, Iron
0165-9936
348-357
Bagshaw, Elizabeth A.
d34b716f-8162-4788-81a8-03146d5528ed
Beaton, Alexander
b33c89f0-5c08-4cbb-9718-51c5c5179ff0
Wadham, Jemma L.
fccc19ee-c691-4f95-bbfd-41f4d4f32c57
Mowlem, Matt
6f633ca2-298f-48ee-a025-ce52dd62124f
Hawkings, Jon R.
6010d694-7b3f-4a03-921e-eb2c8cfd54d3
Tranter, Martyn
42ff1b9c-b38f-4943-ab73-2c2d71d2c48b
Bagshaw, Elizabeth A.
d34b716f-8162-4788-81a8-03146d5528ed
Beaton, Alexander
b33c89f0-5c08-4cbb-9718-51c5c5179ff0
Wadham, Jemma L.
fccc19ee-c691-4f95-bbfd-41f4d4f32c57
Mowlem, Matt
6f633ca2-298f-48ee-a025-ce52dd62124f
Hawkings, Jon R.
6010d694-7b3f-4a03-921e-eb2c8cfd54d3
Tranter, Martyn
42ff1b9c-b38f-4943-ab73-2c2d71d2c48b

Bagshaw, Elizabeth A., Beaton, Alexander, Wadham, Jemma L., Mowlem, Matt, Hawkings, Jon R. and Tranter, Martyn (2016) Chemical sensors for in situ data collection in the cryosphere. Trends in Analytical Chemistry, 82, 348-357. (doi:10.1016/j.trac.2016.06.016).

Record type: Article

Abstract

Glaciers and ice sheets are recognised as important components of global biogeochemical cycles. Chemical sensors have great potential for in situ monitoring in the cryosphere and are available for many analytes of interest, but they are frequently unsuitable for deployment since meltwaters are cold, turbid, experience freeze-thaw cycles and display low ionic strength and concentrations of target analytes. Here, we review in situ chemical sensors currently available for measurement of biogeochemically important analytes and assess their suitability for deployment. These include standard parameters such as dissolved oxygen and pH, along with macronutrients (nitrate/nitrite and phosphate), micronutrients (iron and manganese) and biogenic gases (methane). Where no commercial alternatives are available, we discuss sensors currently in development, and their applicability to these extreme environments. The information presented has great relevance for future science in polar environments, and for the ultimate goal of obtaining in situ data from extreme, inaccessible subglacial environments.

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Published date: 1 September 2016
Keywords: Cryosphere, Chemical sensors, Glacial meltwater, Oxygen, pH, Methane, Nitrate, Phosphate, Iron
Organisations: Ocean Technology and Engineering

Identifiers

Local EPrints ID: 404811
URI: http://eprints.soton.ac.uk/id/eprint/404811
ISSN: 0165-9936
PURE UUID: 444de306-059a-46c3-a216-3af21306cebb
ORCID for Matt Mowlem: ORCID iD orcid.org/0000-0001-7613-6121

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Date deposited: 16 Jan 2017 16:22
Last modified: 16 Mar 2024 03:08

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Contributors

Author: Elizabeth A. Bagshaw
Author: Alexander Beaton
Author: Jemma L. Wadham
Author: Matt Mowlem ORCID iD
Author: Jon R. Hawkings
Author: Martyn Tranter

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