Multiphoton transitions for the harmonic oscillator
Multiphoton transitions for the harmonic oscillator
2- and 3-photon electric dipole transitions for the harmonic oscillator are shown to have zero intensity. This is extended to the general cases of ? v = n and ? v = n ?2 for n -photon transitions. Although not proved in general, it seems likely that all multiphoton transition moments vanish. This suggests that electric dipole multiphoton transition intensity is due to anharmonicity.
2523-2525
Frey, J.G.
ba60c559-c4af-44f1-87e6-ce69819bf23f
King, R.C.
76ae9fb3-6b19-449d-8583-dbf1d7ed2706
Moss, R.E.
5d410492-850a-4950-85fd-2deb89f60859
10 August 2006
Frey, J.G.
ba60c559-c4af-44f1-87e6-ce69819bf23f
King, R.C.
76ae9fb3-6b19-449d-8583-dbf1d7ed2706
Moss, R.E.
5d410492-850a-4950-85fd-2deb89f60859
Frey, J.G., King, R.C. and Moss, R.E.
(2006)
Multiphoton transitions for the harmonic oscillator.
Molecular Physics, 104 (15), .
(doi:10.1080/00268970600798038).
Abstract
2- and 3-photon electric dipole transitions for the harmonic oscillator are shown to have zero intensity. This is extended to the general cases of ? v = n and ? v = n ?2 for n -photon transitions. Although not proved in general, it seems likely that all multiphoton transition moments vanish. This suggests that electric dipole multiphoton transition intensity is due to anharmonicity.
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Published date: 10 August 2006
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Local EPrints ID: 41208
URI: http://eprints.soton.ac.uk/id/eprint/41208
ISSN: 0026-8976
PURE UUID: 06e6fa0d-c967-455e-ab2a-01116b890a14
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Date deposited: 28 Jul 2006
Last modified: 16 Mar 2024 02:34
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Author:
R.C. King
Author:
R.E. Moss
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