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New semiconducting radical-cation salts of chiral bis(2-hydroxylpropylthio)ethylenedithio TTF

New semiconducting radical-cation salts of chiral bis(2-hydroxylpropylthio)ethylenedithio TTF
New semiconducting radical-cation salts of chiral bis(2-hydroxylpropylthio)ethylenedithio TTF
Electrocrystallisations of the chiral donor molecule S,S-bis(2-hydroxylpropylthio)ethylenedithiotetrathiafulvalene have produced a series of 1 : 1 semiconducting radical-cation salts with anions bromide, chloride, perchlorate and hexafluorophosphate. The flexibility and hydrogen bonding ability of the donor's chiral side chains lead to three quite different packing arrangements of donor cation pairs. Conductivity is maintained despite significant separations of donor cation pairs in some cases.
1466-8033
4848-4856
Lopez, Jordan R.
e8b78839-cb73-497f-b7d3-d120281aa258
Martin, Lee
40bf71a6-83ea-41de-a1ff-711043af2d00
Wallis, John D.
bc777046-08c0-40bf-9cfd-3a69481bb06a
Akutsu, Hiroki
86a57ad8-7b6f-4df2-be69-25b1c08d9a6c
Yamada, Jun-ichi
dabccccb-fecf-4b4e-b022-fe7b2a984d82
Nakatsuji, Shin-ichi
6564711f-b8d5-405b-8594-a11880d7ff75
Wilson, Claire
6be18134-9a9f-4d19-8197-0593a648773f
Christensen, Jeppe
f37d3a1e-05d9-4144-8af2-bd29ead7d9c3
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Lopez, Jordan R.
e8b78839-cb73-497f-b7d3-d120281aa258
Martin, Lee
40bf71a6-83ea-41de-a1ff-711043af2d00
Wallis, John D.
bc777046-08c0-40bf-9cfd-3a69481bb06a
Akutsu, Hiroki
86a57ad8-7b6f-4df2-be69-25b1c08d9a6c
Yamada, Jun-ichi
dabccccb-fecf-4b4e-b022-fe7b2a984d82
Nakatsuji, Shin-ichi
6564711f-b8d5-405b-8594-a11880d7ff75
Wilson, Claire
6be18134-9a9f-4d19-8197-0593a648773f
Christensen, Jeppe
f37d3a1e-05d9-4144-8af2-bd29ead7d9c3
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8

Lopez, Jordan R., Martin, Lee, Wallis, John D., Akutsu, Hiroki, Yamada, Jun-ichi, Nakatsuji, Shin-ichi, Wilson, Claire, Christensen, Jeppe and Coles, Simon J. (2017) New semiconducting radical-cation salts of chiral bis(2-hydroxylpropylthio)ethylenedithio TTF. CrystEngComm, 19 (32), 4848-4856. (doi:10.1039/c7ce01014a).

Record type: Article

Abstract

Electrocrystallisations of the chiral donor molecule S,S-bis(2-hydroxylpropylthio)ethylenedithiotetrathiafulvalene have produced a series of 1 : 1 semiconducting radical-cation salts with anions bromide, chloride, perchlorate and hexafluorophosphate. The flexibility and hydrogen bonding ability of the donor's chiral side chains lead to three quite different packing arrangements of donor cation pairs. Conductivity is maintained despite significant separations of donor cation pairs in some cases.

Text
Lee Revised 19th July DONOR PF6 ClO4 Cl Br - Copy - Accepted Manuscript
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More information

Accepted/In Press date: 21 July 2017
e-pub ahead of print date: 2 August 2017
Published date: 28 August 2017

Identifiers

Local EPrints ID: 413431
URI: https://eprints.soton.ac.uk/id/eprint/413431
ISSN: 1466-8033
PURE UUID: 4db93f7b-dcda-4894-87b0-f18f46669f52
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 24 Aug 2017 16:30
Last modified: 31 Jul 2019 04:38

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Contributors

Author: Jordan R. Lopez
Author: Lee Martin
Author: John D. Wallis
Author: Hiroki Akutsu
Author: Jun-ichi Yamada
Author: Shin-ichi Nakatsuji
Author: Claire Wilson
Author: Jeppe Christensen
Author: Simon J. Coles ORCID iD

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