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Effect of incarcerated HF on the exohedral chemical reactivity of HF@C60

Effect of incarcerated HF on the exohedral chemical reactivity of HF@C60
Effect of incarcerated HF on the exohedral chemical reactivity of HF@C60
The first chemical modification on the brand new endohedral HF@C60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-trans- pyrrolidino[3,4:1,2][60]fullerene 2b has been studied and compared with empty C60 (2a) and endohedral H2O@C60 (3). The comparative study shows a kinetic order for the isomerization process of H2O@C60 4 HF@C60 4 C60, thus confirming the effect of the incarcerated species on the zwitterionic intermediate stability.
1359-7345
10993-10996
Vidal, Sara
cba50932-1a6c-490d-82e4-83f434469f44
Alom, Shamim
f6b56fb1-7f94-432a-87cd-887f6e5d9f64
Izquierdo, Marta
12b96929-2967-438a-b55d-8a92a4e4ffae
Garcia-Borras, Marc
7fd597ea-fb74-4067-a316-9767d0fd3c37
Filippone, Salvatore
c306d749-8db9-41e5-b1aa-98e9b127b9ee
Osuna, Silvia
2d708cfd-3b91-41d4-b3ab-48faea5eda1f
Sola, Miquel
c7a5ecee-275f-44be-9829-d620c34227db
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
Martin, Nazario
52b556d4-5c04-4e8d-a436-d6527011edba
Vidal, Sara
cba50932-1a6c-490d-82e4-83f434469f44
Alom, Shamim
f6b56fb1-7f94-432a-87cd-887f6e5d9f64
Izquierdo, Marta
12b96929-2967-438a-b55d-8a92a4e4ffae
Garcia-Borras, Marc
7fd597ea-fb74-4067-a316-9767d0fd3c37
Filippone, Salvatore
c306d749-8db9-41e5-b1aa-98e9b127b9ee
Osuna, Silvia
2d708cfd-3b91-41d4-b3ab-48faea5eda1f
Sola, Miquel
c7a5ecee-275f-44be-9829-d620c34227db
Whitby, Richard J.
45632236-ab00-4ad0-a02d-6209043e818b
Martin, Nazario
52b556d4-5c04-4e8d-a436-d6527011edba

Vidal, Sara, Alom, Shamim, Izquierdo, Marta, Garcia-Borras, Marc, Filippone, Salvatore, Osuna, Silvia, Sola, Miquel, Whitby, Richard J. and Martin, Nazario (2017) Effect of incarcerated HF on the exohedral chemical reactivity of HF@C60. Chemical Communications, 53 (80), 10993-10996. (doi:10.1039/c7cc05987f).

Record type: Article

Abstract

The first chemical modification on the brand new endohedral HF@C60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-trans- pyrrolidino[3,4:1,2][60]fullerene 2b has been studied and compared with empty C60 (2a) and endohedral H2O@C60 (3). The comparative study shows a kinetic order for the isomerization process of H2O@C60 4 HF@C60 4 C60, thus confirming the effect of the incarcerated species on the zwitterionic intermediate stability.

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C7CC05987F Accepted article - Accepted Manuscript
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Accepted/In Press date: 18 August 2017
e-pub ahead of print date: 18 August 2017
Published date: 14 October 2017

Identifiers

Local EPrints ID: 413670
URI: https://eprints.soton.ac.uk/id/eprint/413670
ISSN: 1359-7345
PURE UUID: 41870569-98e8-44ec-875d-15c9732c1387
ORCID for Richard J. Whitby: ORCID iD orcid.org/0000-0002-9891-5502

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Date deposited: 31 Aug 2017 16:31
Last modified: 14 Mar 2019 05:37

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