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UVA variability overrules UVB ozone depletion effects on the photoreduction of iron in the Southern Ocean

Record type: Article

A spectral weighting function describing the wavelength dependency of the photoproduction of Fe( II) in Antarctic seawater was established. The strong wavelength-dependent photoproduction of Fe( II) from amorphous ferric hydroxides can be described as an exponential function: epsilon(lambda) = 3.57 . 10(3) . e (-0.02)((lambda-300)). Solar spectra recorded during the 2000 Antarctic ozone depletion season were used to demonstrate that daily and seasonal variability of the ultraviolet A ( UVA: 315-400 nm) and the visible part of the light spectrum (VIS: 400-700 nm) dominates Fe( II) production rates in surface waters ( respectively > 60% and about 30%) and in the water column. Although ultraviolet B ( UVB: 280-315 nm) is the most effective wavelength region for Fe( II) photoproduction, the impact of UVB was small due to the relatively low flux of UVB into the ocean surface waters. However, the impact of UVB did indeed increase significantly from 3.54 to 6.15 % during the austral ozone minimum.

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Citation

Rijkenberg, Micha J.A., Gerringa, Loes J.A., Neale, Patrick J., Timmermans, Klaas R., Buma, Anita G.J. and de Baar, Hein J.W. (2004) UVA variability overrules UVB ozone depletion effects on the photoreduction of iron in the Southern Ocean Geophysical Research Letters, 31, (24), L24310. (doi:10.1029/2004GL020829).

More information

Published date: 2004
Keywords: ultraviolet-radiation, equatorial pacific, waters, photosynthesis, phytoplankton, inhibition, seawater, ice
Organisations: Ocean and Earth Science

Identifiers

Local EPrints ID: 41429
URI: http://eprints.soton.ac.uk/id/eprint/41429
ISSN: 0094-8276
PURE UUID: 05fdfe27-f727-417b-bdc5-40083b6814c6

Catalogue record

Date deposited: 12 Sep 2006
Last modified: 17 Jul 2017 15:30

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Contributors

Author: Micha J.A. Rijkenberg
Author: Loes J.A. Gerringa
Author: Patrick J. Neale
Author: Klaas R. Timmermans
Author: Anita G.J. Buma
Author: Hein J.W. de Baar

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