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Using orthogonal projection approach (OPA) for rank-deficient reaction processes

Using orthogonal projection approach (OPA) for rank-deficient reaction processes
Using orthogonal projection approach (OPA) for rank-deficient reaction processes

Orthogonal projection approach (OPA) has been used for monitoring batch processes. However, because of the mass balance constraints between the reactants and products in a chemical reaction, standard OPA will fail if rank-deficiency occurs. The effect of the rank-deficiency on using OPA for process reaction data sets is discussed, and a new automatic approach for resolution of rank-deficiency data sets by OPA is proposed for batch control. The method is demonstrated for an industrial batch data set.

Batch process, Orthogonal projection approach (OPA), Rank-deficiency
0169-7439
3-12
Xu, C. J.
1c4d76ae-4c68-4688-8ef6-88ef2529a436
Gourvénec, S.
6ff91ad8-1a91-42fe-a3f4-1b5d6f5ce0b8
Liang, Y. Z.
30f08ba1-1b92-4d5c-9a36-8a6059f302ef
Massart, D. L.
e45e44fe-05dd-4936-89f0-85fe53999ce5
Xu, C. J.
1c4d76ae-4c68-4688-8ef6-88ef2529a436
Gourvénec, S.
6ff91ad8-1a91-42fe-a3f4-1b5d6f5ce0b8
Liang, Y. Z.
30f08ba1-1b92-4d5c-9a36-8a6059f302ef
Massart, D. L.
e45e44fe-05dd-4936-89f0-85fe53999ce5

Xu, C. J., Gourvénec, S., Liang, Y. Z. and Massart, D. L. (2006) Using orthogonal projection approach (OPA) for rank-deficient reaction processes. Chemometrics and Intelligent Laboratory Systems, 81 (1), 3-12. (doi:10.1016/j.chemolab.2005.01.004).

Record type: Article

Abstract

Orthogonal projection approach (OPA) has been used for monitoring batch processes. However, because of the mass balance constraints between the reactants and products in a chemical reaction, standard OPA will fail if rank-deficiency occurs. The effect of the rank-deficiency on using OPA for process reaction data sets is discussed, and a new automatic approach for resolution of rank-deficiency data sets by OPA is proposed for batch control. The method is demonstrated for an industrial batch data set.

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More information

Published date: March 2006
Keywords: Batch process, Orthogonal projection approach (OPA), Rank-deficiency

Identifiers

Local EPrints ID: 414550
URI: http://eprints.soton.ac.uk/id/eprint/414550
ISSN: 0169-7439
PURE UUID: eef5c7d1-f589-446d-9530-80c3e5c4dd1c
ORCID for S. Gourvénec: ORCID iD orcid.org/0000-0002-2628-7914

Catalogue record

Date deposited: 04 Oct 2017 16:30
Last modified: 16 Mar 2024 04:31

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Contributors

Author: C. J. Xu
Author: S. Gourvénec ORCID iD
Author: Y. Z. Liang
Author: D. L. Massart

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