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Investigating the structure directing properties of designer 1,8-naphthalimide and amphiphilic sulfonate anions and their FeIII thiosemicarbazone complexes

Investigating the structure directing properties of designer 1,8-naphthalimide and amphiphilic sulfonate anions and their FeIII thiosemicarbazone complexes
Investigating the structure directing properties of designer 1,8-naphthalimide and amphiphilic sulfonate anions and their FeIII thiosemicarbazone complexes
A series of FeIII thiosemicarbazone complexes featuring novel 1,8-naphthalimide sulfonate-based anions was prepared, and the structure directing properties were investigated. The designer naphthalimide-based anions show interesting structure extension though π-stacking in the solid state. In addition, a long chain sulfonate anion was incorporated to introduce amphiphilicity to the complex and allow for formation of Langmuir−Blodgett films.
1528-7483
5129-5144
Carter, Anthony B.
716d0f93-55b4-497e-9081-8e84b7104b65
Laverick, Robert J.
5e47a285-e2d9-4da7-9e2b-fd508692fe74
Wales, Dominic J.
c001ff27-d3ac-4d2e-859f-9e963fc0374c
Akponasa, Sarah O.
06711786-e1bc-4057-b647-e6edbbfbe57a
Scott, Aaron J.
6f3935c9-4a9e-443f-9abe-7e38b61d7a2b
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Carter, Anthony B.
716d0f93-55b4-497e-9081-8e84b7104b65
Laverick, Robert J.
5e47a285-e2d9-4da7-9e2b-fd508692fe74
Wales, Dominic J.
c001ff27-d3ac-4d2e-859f-9e963fc0374c
Akponasa, Sarah O.
06711786-e1bc-4057-b647-e6edbbfbe57a
Scott, Aaron J.
6f3935c9-4a9e-443f-9abe-7e38b61d7a2b
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6

Carter, Anthony B., Laverick, Robert J., Wales, Dominic J., Akponasa, Sarah O., Scott, Aaron J., Keene, Tony D. and Kitchen, Jonathan A. (2017) Investigating the structure directing properties of designer 1,8-naphthalimide and amphiphilic sulfonate anions and their FeIII thiosemicarbazone complexes. Crystal Growth & Design, 17 (10), 5129-5144. (doi:10.1021/acs.cgd.7b00534).

Record type: Article

Abstract

A series of FeIII thiosemicarbazone complexes featuring novel 1,8-naphthalimide sulfonate-based anions was prepared, and the structure directing properties were investigated. The designer naphthalimide-based anions show interesting structure extension though π-stacking in the solid state. In addition, a long chain sulfonate anion was incorporated to introduce amphiphilicity to the complex and allow for formation of Langmuir−Blodgett films.

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Cryst_Growth_Des_Naphthalimide_anions - Accepted Manuscript
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Accepted/In Press date: 5 September 2017
e-pub ahead of print date: 5 September 2017
Published date: 4 October 2017
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Identifiers

Local EPrints ID: 415338
URI: http://eprints.soton.ac.uk/id/eprint/415338
DOI: doi:10.1021/acs.cgd.7b00534
ISSN: 1528-7483
PURE UUID: fdf9b4a8-3cc8-4aa4-8992-b97092a0aebf
ORCID for Tony D. Keene: ORCID iD orcid.org/0000-0003-2297-4327
ORCID for Jonathan A. Kitchen: ORCID iD orcid.org/0000-0002-7139-5666

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Date deposited: 07 Nov 2017 17:30
Last modified: 16 Mar 2024 05:53

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Contributors

Author: Anthony B. Carter
Author: Robert J. Laverick
Author: Dominic J. Wales
Author: Sarah O. Akponasa
Author: Aaron J. Scott
Author: Tony D. Keene ORCID iD
Author: Jonathan A. Kitchen ORCID iD

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