The University of Southampton
University of Southampton Institutional Repository
Warning ePrints Soton is experiencing an issue with some file downloads not being available. We are working hard to fix this. Please bear with us.

Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs

Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs
Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs
A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(II) gave IMP-18 – a 3D MOF incorporating Si–O–Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(II).
1359-7345
12524-12527
Delmas, Luke C.
ccaba93d-7e00-49c8-96ce-fd12d719deca
Horton, Peter
154c8930-bfc3-495b-ad4a-8a278d5da3a5
White, Andrew J.P.
09c64321-ac83-40be-a22c-3d62e4b19a7e
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Lickiss, Paul D.
dc0ce1d4-daea-452f-b0ef-77c9c62c5df8
Davies, Robert P.
37552576-6a8d-4dbc-af70-12870f40a048
Delmas, Luke C.
ccaba93d-7e00-49c8-96ce-fd12d719deca
Horton, Peter
154c8930-bfc3-495b-ad4a-8a278d5da3a5
White, Andrew J.P.
09c64321-ac83-40be-a22c-3d62e4b19a7e
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Lickiss, Paul D.
dc0ce1d4-daea-452f-b0ef-77c9c62c5df8
Davies, Robert P.
37552576-6a8d-4dbc-af70-12870f40a048

Delmas, Luke C., Horton, Peter, White, Andrew J.P., Coles, Simon J., Lickiss, Paul D. and Davies, Robert P. (2017) Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs. Chemical Communications, 2017 (53), 12524-12527. (doi:10.1039/c7cc06022j).

Record type: Article

Abstract

A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(II) gave IMP-18 – a 3D MOF incorporating Si–O–Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(II).

Text
c7cc06022j - Version of Record
Available under License Creative Commons Attribution.
Download (2MB)

More information

Accepted/In Press date: 22 September 2017
e-pub ahead of print date: 6 November 2017

Identifiers

Local EPrints ID: 416076
URI: http://eprints.soton.ac.uk/id/eprint/416076
ISSN: 1359-7345
PURE UUID: 16c3f908-ba14-4ab0-a946-c74d4a34b265
ORCID for Peter Horton: ORCID iD orcid.org/0000-0001-8886-2016
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 01 Dec 2017 17:30
Last modified: 22 Nov 2021 02:45

Export record

Altmetrics

Contributors

Author: Luke C. Delmas
Author: Peter Horton ORCID iD
Author: Andrew J.P. White
Author: Simon J. Coles ORCID iD
Author: Paul D. Lickiss
Author: Robert P. Davies

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×