Luminescent 1,8-naphthalimide-derived Re^I complexes: Syntheses, spectroscopy, x-ray structure and preliminary bioimaging in fission yeast cells

Abstract

A series of picolyl-functionalised, fluorescent 1,8-naphthalimide ligands (L) have been synthesised and coordinated to ReI to form luminescent cationic complexes of the general form fac-[Re(phen)(CO)3(L)]BF4. The complexes were characterised by using a range of spectroscopic and analytical techniques. One example of a complex was also characterised in the solid-state by using single-crystal X-ray diffraction, revealing a distorted octahedral coordination sphere at ReI and Re–C/Re–N bond lengths within the expected ranges. All ligands were shown to be fluorescent, with the 4-amino derivatives showing intramolecular charge transfer in the visible region (511–534 nm). The complexes generally showed a mixture of ligand-centred and/or 3MLCT emission depending upon the nature of the coordinated 1,8-naphthalimide ligand. For selected complexes, confocal fluorescence microscopy was undertaken by using fission yeast cells (Schizosaccharomyces pombe) and showed that the structure of the 1,8-naphthalimide ligand influences the uptake and localisation of the rhenium complex.

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Identifiers

ORCID for Simon J. Coles: orcid.org/0000-0001-8414-9272

ORCID for Peter N. Horton: orcid.org/0000-0001-8886-2016

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