Polynuclear ampyrone based 3d coordination clusters
Polynuclear ampyrone based 3d coordination clusters
The use of the monoanionic Schiff base ligand (E)-4-(2-hydroxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one in transition (Co, Ni and Cu) coordination chemistry yields mono-, tetra- and pentanuclear Coordination Clusters with different structural motifs. An organic transformation occurs in the ligand in the Cu compound for which theoretical studies are presented. Solution studies, topological issues and magnetic studies are discussed. The present results demonstrate the richness of the coordination chemistry of this monoprotic organic ligand, which promotes the formation of high-nuclearity CCs.
1411-1421
Sampani, Stavroula I.
346af07d-2a76-47b8-b21d-7416ebb69efc
Loukopoulos, Edward
0c3abad3-9ed4-46cd-b03f-9cbb2fd3fff7
Azam, Mohammad
f4f23853-6f6f-4000-9f03-113f40e9d5d2
Griffiths, Kieran
91984c79-162c-4653-8521-60b3e76764f2
Abdul-Sada, Alaa
03b55c32-8062-4b73-926d-f243ca078a83
Tizzard, Graham J.
8474c0fa-40df-43a6-a662-7f3c4722dbf2
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Escuer, Albert
b0ec9089-81bf-4f1a-9093-a7c032d02f76
Tsipis, Athanassios C.
16b23a31-6d5d-4031-9502-bc11de5fc47d
Kostakis, George E.
dd72c724-c82e-4891-aa68-ccdb42cc6cb8
14 March 2018
Sampani, Stavroula I.
346af07d-2a76-47b8-b21d-7416ebb69efc
Loukopoulos, Edward
0c3abad3-9ed4-46cd-b03f-9cbb2fd3fff7
Azam, Mohammad
f4f23853-6f6f-4000-9f03-113f40e9d5d2
Griffiths, Kieran
91984c79-162c-4653-8521-60b3e76764f2
Abdul-Sada, Alaa
03b55c32-8062-4b73-926d-f243ca078a83
Tizzard, Graham J.
8474c0fa-40df-43a6-a662-7f3c4722dbf2
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Escuer, Albert
b0ec9089-81bf-4f1a-9093-a7c032d02f76
Tsipis, Athanassios C.
16b23a31-6d5d-4031-9502-bc11de5fc47d
Kostakis, George E.
dd72c724-c82e-4891-aa68-ccdb42cc6cb8
Sampani, Stavroula I., Loukopoulos, Edward, Azam, Mohammad, Griffiths, Kieran, Abdul-Sada, Alaa, Tizzard, Graham J., Coles, Simon J., Escuer, Albert, Tsipis, Athanassios C. and Kostakis, George E.
(2018)
Polynuclear ampyrone based 3d coordination clusters.
CrystEngComm, 20, .
(doi:10.1039/C7CE02093G).
Abstract
The use of the monoanionic Schiff base ligand (E)-4-(2-hydroxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one in transition (Co, Ni and Cu) coordination chemistry yields mono-, tetra- and pentanuclear Coordination Clusters with different structural motifs. An organic transformation occurs in the ligand in the Cu compound for which theoretical studies are presented. Solution studies, topological issues and magnetic studies are discussed. The present results demonstrate the richness of the coordination chemistry of this monoprotic organic ligand, which promotes the formation of high-nuclearity CCs.
Text
Manuscript_accepted
- Accepted Manuscript
More information
Accepted/In Press date: 28 January 2018
e-pub ahead of print date: 29 January 2018
Published date: 14 March 2018
Identifiers
Local EPrints ID: 417815
URI: http://eprints.soton.ac.uk/id/eprint/417815
ISSN: 1466-8033
PURE UUID: e4bec2c0-fe21-4692-ae6a-de1847f98541
Catalogue record
Date deposited: 14 Feb 2018 17:30
Last modified: 16 Mar 2024 06:11
Export record
Altmetrics
Contributors
Author:
Stavroula I. Sampani
Author:
Edward Loukopoulos
Author:
Mohammad Azam
Author:
Kieran Griffiths
Author:
Alaa Abdul-Sada
Author:
Albert Escuer
Author:
Athanassios C. Tsipis
Author:
George E. Kostakis
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
