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A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*

A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*
A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*

We report the synthesis of a tripodal tris-selenourea transporter scaffold. The Cl− and (Formula presented.) transport activity of the compound has been compared extensively with the analogous oxo- and thiourea compounds. We found that the selenourea demonstrates remarkably similar transport efficacy and mechanistic properties to the equivalent thiourea, but demonstrates flipped selectivity for Cl− over (Formula presented.).

anion transport, hydrogen bonding, selenourea, Supramolecular chemistry
1061-0278
1-6
Spooner, Michael J.
bb6ca5e3-f485-4025-900f-8945fd47f461
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Spooner, Michael J.
bb6ca5e3-f485-4025-900f-8945fd47f461
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943

Spooner, Michael J. and Gale, Philip A. (2018) A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*. Supramolecular Chemistry, 1-6. (doi:10.1080/10610278.2018.1431394).

Record type: Article

Abstract

We report the synthesis of a tripodal tris-selenourea transporter scaffold. The Cl− and (Formula presented.) transport activity of the compound has been compared extensively with the analogous oxo- and thiourea compounds. We found that the selenourea demonstrates remarkably similar transport efficacy and mechanistic properties to the equivalent thiourea, but demonstrates flipped selectivity for Cl− over (Formula presented.).

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More information

Accepted/In Press date: 17 January 2018
e-pub ahead of print date: 8 February 2018
Related URLs:
Keywords: anion transport, hydrogen bonding, selenourea, Supramolecular chemistry
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Identifiers

Local EPrints ID: 418238
URI: http://eprints.soton.ac.uk/id/eprint/418238
DOI: doi:10.1080/10610278.2018.1431394
ISSN: 1061-0278
PURE UUID: 11ea6662-eb38-465a-b08b-e48f52fb1a43
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 26 Feb 2018 17:30
Last modified: 06 Jun 2024 01:38

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Contributors

Author: Michael J. Spooner
Author: Philip A. Gale ORCID iD

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