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A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*

A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*
A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*

We report the synthesis of a tripodal tris-selenourea transporter scaffold. The Cl and (Formula presented.) transport activity of the compound has been compared extensively with the analogous oxo- and thiourea compounds. We found that the selenourea demonstrates remarkably similar transport efficacy and mechanistic properties to the equivalent thiourea, but demonstrates flipped selectivity for Cl over (Formula presented.).

anion transport, hydrogen bonding, selenourea, Supramolecular chemistry
1061-0278
1-6
Spooner, Michael J.
bb6ca5e3-f485-4025-900f-8945fd47f461
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Spooner, Michael J.
bb6ca5e3-f485-4025-900f-8945fd47f461
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943

Spooner, Michael J. and Gale, Philip A. (2018) A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*. Supramolecular Chemistry, 1-6. (doi:10.1080/10610278.2018.1431394).

Record type: Article

Abstract

We report the synthesis of a tripodal tris-selenourea transporter scaffold. The Cl and (Formula presented.) transport activity of the compound has been compared extensively with the analogous oxo- and thiourea compounds. We found that the selenourea demonstrates remarkably similar transport efficacy and mechanistic properties to the equivalent thiourea, but demonstrates flipped selectivity for Cl over (Formula presented.).

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More information

Accepted/In Press date: 17 January 2018
e-pub ahead of print date: 8 February 2018
Keywords: anion transport, hydrogen bonding, selenourea, Supramolecular chemistry

Identifiers

Local EPrints ID: 418238
URI: http://eprints.soton.ac.uk/id/eprint/418238
ISSN: 1061-0278
PURE UUID: 11ea6662-eb38-465a-b08b-e48f52fb1a43
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 26 Feb 2018 17:30
Last modified: 15 Sep 2021 01:44

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Contributors

Author: Michael J. Spooner
Author: Philip A. Gale ORCID iD

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