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Chelating rotaxane ligands as fluorescent sensors for metal ion

Chelating rotaxane ligands as fluorescent sensors for metal ion
Chelating rotaxane ligands as fluorescent sensors for metal ion
Although metal‐ion‐binding interlocked molecules have been under intense investigation for over three decades, their application as scaffolds for the development of sensors for metal ions remains underexplored. In this work, we demonstrate the potential of simple rotaxanes as metal‐ion‐responsive ligand scaffolds through the development of a proof‐of‐concept selective sensor for Zn2+.
rotaxane, sensor, Supramolecular chemistry
1433-7851
5310-5314
Denis, Mathieu
05f9a9b4-df98-4cc8-bebf-33e99bc91e7d
Pancholi, Jessica
96a1502b-a806-4bff-a60e-139ca1ff6129
Jobe, Kajally
4ae810b8-0a8f-464c-af3d-9a75b822db30
Watkinson, Michael
71738595-901b-4bca-98b8-bc5d1487d2fe
Goldup, Stephen
0a93eedd-98bb-42c1-a963-e2815665e937
Denis, Mathieu
05f9a9b4-df98-4cc8-bebf-33e99bc91e7d
Pancholi, Jessica
96a1502b-a806-4bff-a60e-139ca1ff6129
Jobe, Kajally
4ae810b8-0a8f-464c-af3d-9a75b822db30
Watkinson, Michael
71738595-901b-4bca-98b8-bc5d1487d2fe
Goldup, Stephen
0a93eedd-98bb-42c1-a963-e2815665e937

Denis, Mathieu, Pancholi, Jessica, Jobe, Kajally, Watkinson, Michael and Goldup, Stephen (2018) Chelating rotaxane ligands as fluorescent sensors for metal ion. Angewandte Chemie International Edition, 57 (19), 5310-5314. (doi:10.1002/anie.201712931).

Record type: Article

Abstract

Although metal‐ion‐binding interlocked molecules have been under intense investigation for over three decades, their application as scaffolds for the development of sensors for metal ions remains underexplored. In this work, we demonstrate the potential of simple rotaxanes as metal‐ion‐responsive ligand scaffolds through the development of a proof‐of‐concept selective sensor for Zn2+.

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rvsd MS Denis Angew Sensors Pure - Accepted Manuscript
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Accepted/In Press date: 5 March 2018
e-pub ahead of print date: 14 March 2018
Published date: 4 May 2018
Keywords: rotaxane, sensor, Supramolecular chemistry
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Identifiers

Local EPrints ID: 418694
URI: http://eprints.soton.ac.uk/id/eprint/418694
DOI: doi:10.1002/anie.201712931
ISSN: 1433-7851
PURE UUID: d1b4685c-8835-43e3-a469-3db04f9cb5a4
ORCID for Stephen Goldup: ORCID iD orcid.org/0000-0003-3781-0464

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Date deposited: 19 Mar 2018 17:30
Last modified: 16 Mar 2024 06:20

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Contributors

Author: Mathieu Denis
Author: Jessica Pancholi
Author: Kajally Jobe
Author: Michael Watkinson
Author: Stephen Goldup ORCID iD

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