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Efficient multi-component active template synthesis of catenanes

Efficient multi-component active template synthesis of catenanes
Efficient multi-component active template synthesis of catenanes
We describe a simple and high yielding active template synthesis of [2]catenanes. In addition to mechanical bond formation using a single pre-macrocycle bearing an azide and alkyne moiety, our method is also suitable for the co-macrocyclisation of readily available bis-alkyne and bis-azide co-monomers and even short alkyne/azide components which oligomerise prior to mechanical bond formation.
0002-7863
4787–4791
Lewis, James E.M.
42b46a03-a7ca-4d3a-96e5-a5c962fc9573
Modicom, Florian
4dbe5553-a5b4-4431-ae8c-8c19a39c0d48
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Lewis, James E.M.
42b46a03-a7ca-4d3a-96e5-a5c962fc9573
Modicom, Florian
4dbe5553-a5b4-4431-ae8c-8c19a39c0d48
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937

Lewis, James E.M., Modicom, Florian and Goldup, Stephen M. (2018) Efficient multi-component active template synthesis of catenanes. Journal of the American Chemical Society, 140 (14), 4787–4791. (doi:10.1021/jacs.8b01602).

Record type: Article

Abstract

We describe a simple and high yielding active template synthesis of [2]catenanes. In addition to mechanical bond formation using a single pre-macrocycle bearing an azide and alkyne moiety, our method is also suitable for the co-macrocyclisation of readily available bis-alkyne and bis-azide co-monomers and even short alkyne/azide components which oligomerise prior to mechanical bond formation.

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Accepted/In Press date: 18 March 2018
e-pub ahead of print date: 20 March 2018
Published date: March 2018

Identifiers

Local EPrints ID: 419000
URI: http://eprints.soton.ac.uk/id/eprint/419000
ISSN: 0002-7863
PURE UUID: 69700d24-9a75-47eb-b0dc-761e76b838d8
ORCID for Stephen M. Goldup: ORCID iD orcid.org/0000-0003-3781-0464

Catalogue record

Date deposited: 27 Mar 2018 16:30
Last modified: 18 Feb 2021 17:24

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Contributors

Author: James E.M. Lewis
Author: Florian Modicom

University divisions

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