Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies

Delmas, Luke C., White, Andrew J.P., Pugh, David, Horton, Peter N., Coles, Simon J., Lickiss, Paul D. and Davies, Robert P. (2018) Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies. CrystEngComm, 20 (32), 4541-4545. (doi:10.1039/c8ce00662h).

Record type: Article

Abstract

A hexacarboxylic acid with a trisiloxane backbone (L-H₆) has been prepared and applied in MOF construction. L-H₆ itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H₆ with Mn(ii) gave IMP-20 and with Zn(ii) gave IMP-21: both are 3D MOFs incorporating Si-O-Si-O-Si linkages.

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Accepted/In Press date: 22 June 2018

e-pub ahead of print date: 2 August 2018

Identifiers

Local EPrints ID: 424474

URI: http://eprints.soton.ac.uk/id/eprint/424474

DOI: doi:10.1039/c8ce00662h

ISSN: 1466-8033

PURE UUID: 2c76cc27-39f4-4706-bc23-683ba11962d5

ORCID for Peter N. Horton:

orcid.org/0000-0001-8886-2016

ORCID for Simon J. Coles:

orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 05 Oct 2018 11:37

Last modified: 29 Oct 2023 02:42

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Contributors

Author: Luke C. Delmas

Author: Andrew J.P. White

Author: David Pugh

Author: Peter N. Horton

Author: Simon J. Coles

Author: Paul D. Lickiss

Author: Robert P. Davies

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