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Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies

Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies
Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies

A hexacarboxylic acid with a trisiloxane backbone (L-H6) has been prepared and applied in MOF construction. L-H6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H6 with Mn(ii) gave IMP-20 and with Zn(ii) gave IMP-21: both are 3D MOFs incorporating Si-O-Si-O-Si linkages.

1466-8033
4541-4545
Delmas, Luke C.
ccaba93d-7e00-49c8-96ce-fd12d719deca
White, Andrew J.P.
ac6dd93b-4f6c-491b-a4b1-7059e02f2dc6
Pugh, David
9ec61267-ae4d-40d8-bebf-0d603e2588d3
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Lickiss, Paul D.
dc0ce1d4-daea-452f-b0ef-77c9c62c5df8
Davies, Robert P.
37552576-6a8d-4dbc-af70-12870f40a048
Delmas, Luke C.
ccaba93d-7e00-49c8-96ce-fd12d719deca
White, Andrew J.P.
ac6dd93b-4f6c-491b-a4b1-7059e02f2dc6
Pugh, David
9ec61267-ae4d-40d8-bebf-0d603e2588d3
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Lickiss, Paul D.
dc0ce1d4-daea-452f-b0ef-77c9c62c5df8
Davies, Robert P.
37552576-6a8d-4dbc-af70-12870f40a048

Delmas, Luke C., White, Andrew J.P., Pugh, David, Horton, Peter N., Coles, Simon J., Lickiss, Paul D. and Davies, Robert P. (2018) Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies. CrystEngComm, 20 (32), 4541-4545. (doi:10.1039/c8ce00662h).

Record type: Article

Abstract

A hexacarboxylic acid with a trisiloxane backbone (L-H6) has been prepared and applied in MOF construction. L-H6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H6 with Mn(ii) gave IMP-20 and with Zn(ii) gave IMP-21: both are 3D MOFs incorporating Si-O-Si-O-Si linkages.

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Accepted/In Press date: 22 June 2018
e-pub ahead of print date: 2 August 2018

Identifiers

Local EPrints ID: 424474
URI: http://eprints.soton.ac.uk/id/eprint/424474
ISSN: 1466-8033
PURE UUID: 2c76cc27-39f4-4706-bc23-683ba11962d5
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

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Date deposited: 05 Oct 2018 11:37
Last modified: 18 Feb 2021 16:54

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Contributors

Author: Luke C. Delmas
Author: Andrew J.P. White
Author: David Pugh
Author: Peter N. Horton ORCID iD
Author: Simon J. Coles ORCID iD
Author: Paul D. Lickiss
Author: Robert P. Davies

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