Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies
Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies
A hexacarboxylic acid with a trisiloxane backbone (L-H6) has been prepared and applied in MOF construction. L-H6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H6 with Mn(ii) gave IMP-20 and with Zn(ii) gave IMP-21: both are 3D MOFs incorporating Si-O-Si-O-Si linkages.
4541-4545
Delmas, Luke C.
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White, Andrew J.P.
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Pugh, David
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Horton, Peter N.
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Coles, Simon J.
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Lickiss, Paul D.
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Davies, Robert P.
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Delmas, Luke C.
ccaba93d-7e00-49c8-96ce-fd12d719deca
White, Andrew J.P.
ac6dd93b-4f6c-491b-a4b1-7059e02f2dc6
Pugh, David
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Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Lickiss, Paul D.
dc0ce1d4-daea-452f-b0ef-77c9c62c5df8
Davies, Robert P.
37552576-6a8d-4dbc-af70-12870f40a048
Delmas, Luke C., White, Andrew J.P., Pugh, David, Horton, Peter N., Coles, Simon J., Lickiss, Paul D. and Davies, Robert P.
(2018)
Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies.
CrystEngComm, 20 (32), .
(doi:10.1039/c8ce00662h).
Abstract
A hexacarboxylic acid with a trisiloxane backbone (L-H6) has been prepared and applied in MOF construction. L-H6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H6 with Mn(ii) gave IMP-20 and with Zn(ii) gave IMP-21: both are 3D MOFs incorporating Si-O-Si-O-Si linkages.
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c8ce00662h
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Accepted/In Press date: 22 June 2018
e-pub ahead of print date: 2 August 2018
Identifiers
Local EPrints ID: 424474
URI: http://eprints.soton.ac.uk/id/eprint/424474
ISSN: 1466-8033
PURE UUID: 2c76cc27-39f4-4706-bc23-683ba11962d5
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Date deposited: 05 Oct 2018 11:37
Last modified: 18 Feb 2021 16:54
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Author:
Luke C. Delmas
Author:
Andrew J.P. White
Author:
David Pugh
Author:
Peter N. Horton
Author:
Paul D. Lickiss
Author:
Robert P. Davies
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