Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies

Delmas, Luke C., White, Andrew J.P., Pugh, David, Horton, Peter N., Coles, Simon J., Lickiss, Paul D. and Davies, Robert P. (2018) Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies. CrystEngComm, 20 (32), 4541-4545. (doi:10.1039/c8ce00662h).

Record type: Article

Abstract

A hexacarboxylic acid with a trisiloxane backbone (L-H₆) has been prepared and applied in MOF construction. L-H₆ itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H₆ with Mn(ii) gave IMP-20 and with Zn(ii) gave IMP-21: both are 3D MOFs incorporating Si-O-Si-O-Si linkages.

Text

c8ce00662h - Version of Record

Available under License Creative Commons Attribution.

Download (1MB)

More information

Accepted/In Press date: 22 June 2018

e-pub ahead of print date: 2 August 2018

Identifiers

Local EPrints ID: 424474

URI: http://eprints.soton.ac.uk/id/eprint/424474

DOI: doi:10.1039/c8ce00662h

ISSN: 1466-8033

PURE UUID: 2c76cc27-39f4-4706-bc23-683ba11962d5

ORCID for Peter N. Horton:

orcid.org/0000-0001-8886-2016

ORCID for Simon J. Coles:

orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 05 Oct 2018 11:37

Last modified: 16 Mar 2024 03:13

Export record

Altmetrics

Share this record

Share this on Facebook Share this on Twitter Share this on Weibo

Contributors

Author: Luke C. Delmas

Author: Andrew J.P. White

Author: David Pugh

Author: Peter N. Horton

Author: Simon J. Coles

Author: Paul D. Lickiss

Author: Robert P. Davies

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information