Facile synthesis of magnetic macroporous polymer/MOF composites as separable catalysts
Facile synthesis of magnetic macroporous polymer/MOF composites as separable catalysts
Design and synthesis of magnetic macroporous metal–organic frameworks (MOFs) have been of significant interest, in order to improve the catalytic efficiency and reusability. In this work, we prepared magnetic macroporous MOF composites based on as-prepared magnetic macroporous polyacrylamides (MMPam). Different MOFs with or without unsaturated coordinative metal sites, including HKUST-1, MOF-2, UiO-66, and Fe-MIL-101(-NH2) were grown on and within the MMPam matrices. The composites showed hierarchical porosity with both micro- and macropores, which facilitated substrate diffusion to increase the conversion for isomerization of α-pinene oxide from 62% in the case of pure HKUST-1 microparticles to 90% in the case of HKUST-1@MMPam. The magnetic property also endowed the composites with easy recovery and reasonable reusability.
metal-organic frameworks, macroporous polymer, magnetic recyclability, heterogeneous catalysis
Chen, Lanjun
1e665fcd-7479-4651-b14b-f97640191dd8
Ding, Xiang
1d54efc7-85b5-4d38-843b-58061d11640d
Huo, Jia
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El Hankari, Samir
1a1ecd2c-cce4-44aa-ac52-c3ac31b80ffb
Bradshaw, Darren
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Chen, Lanjun
1e665fcd-7479-4651-b14b-f97640191dd8
Ding, Xiang
1d54efc7-85b5-4d38-843b-58061d11640d
Huo, Jia
962a200d-5811-424f-b7af-9f98e9c9ae47
El Hankari, Samir
1a1ecd2c-cce4-44aa-ac52-c3ac31b80ffb
Bradshaw, Darren
7677b11e-1961-447e-b9ba-4847a74bd4dd
Chen, Lanjun, Ding, Xiang, Huo, Jia, El Hankari, Samir and Bradshaw, Darren
(2018)
Facile synthesis of magnetic macroporous polymer/MOF composites as separable catalysts.
Journal of Materials Science.
(doi:10.1007/s10853-018-2835-x).
Abstract
Design and synthesis of magnetic macroporous metal–organic frameworks (MOFs) have been of significant interest, in order to improve the catalytic efficiency and reusability. In this work, we prepared magnetic macroporous MOF composites based on as-prepared magnetic macroporous polyacrylamides (MMPam). Different MOFs with or without unsaturated coordinative metal sites, including HKUST-1, MOF-2, UiO-66, and Fe-MIL-101(-NH2) were grown on and within the MMPam matrices. The composites showed hierarchical porosity with both micro- and macropores, which facilitated substrate diffusion to increase the conversion for isomerization of α-pinene oxide from 62% in the case of pure HKUST-1 microparticles to 90% in the case of HKUST-1@MMPam. The magnetic property also endowed the composites with easy recovery and reasonable reusability.
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Accepted/In Press date: 20 August 2018
e-pub ahead of print date: 5 September 2018
Keywords:
metal-organic frameworks, macroporous polymer, magnetic recyclability, heterogeneous catalysis
Identifiers
Local EPrints ID: 425055
URI: http://eprints.soton.ac.uk/id/eprint/425055
ISSN: 0022-2461
PURE UUID: 3646fa33-a09c-42f1-ab75-a0c63e617857
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Date deposited: 09 Oct 2018 16:30
Last modified: 16 Mar 2024 07:05
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Contributors
Author:
Lanjun Chen
Author:
Xiang Ding
Author:
Jia Huo
Author:
Samir El Hankari
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