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One-pot conversion of phospholide ions into β-functional phosphinines

One-pot conversion of phospholide ions into β-functional phosphinines
One-pot conversion of phospholide ions into β-functional phosphinines

Only a few β-functional phosphinines are known. As a result, the reactivity of this class of compounds is almost unexplored. A straightforward access to such compounds from the readily available phospholide ions is described (see scheme) and the reaction mechanism is explored by theoretical methods.

Density functional calculations, Heterocycles, Phosphinines, Phosphorus, Reaction mechanisms
1433-7851
1082-1084
Grundy, Joanna
0bc72187-8dce-41fc-b809-93a6adbe0980
Mathey, François
2458d0d2-7850-4abc-bd56-0da36fc7c8ff
Grundy, Joanna
0bc72187-8dce-41fc-b809-93a6adbe0980
Mathey, François
2458d0d2-7850-4abc-bd56-0da36fc7c8ff

Grundy, Joanna and Mathey, François (2005) One-pot conversion of phospholide ions into β-functional phosphinines. Angewandte Chemie International Edition, 44 (7), 1082-1084. (doi:10.1002/anie.200462020).

Record type: Article

Abstract

Only a few β-functional phosphinines are known. As a result, the reactivity of this class of compounds is almost unexplored. A straightforward access to such compounds from the readily available phospholide ions is described (see scheme) and the reaction mechanism is explored by theoretical methods.

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More information

e-pub ahead of print date: 20 January 2005
Published date: 4 February 2005
Keywords: Density functional calculations, Heterocycles, Phosphinines, Phosphorus, Reaction mechanisms

Identifiers

Local EPrints ID: 426199
URI: http://eprints.soton.ac.uk/id/eprint/426199
ISSN: 1433-7851
PURE UUID: d678b7fa-0432-4d3a-a643-bcdb69b95967

Catalogue record

Date deposited: 16 Nov 2018 17:30
Last modified: 16 Nov 2018 17:30

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