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Phosphaguanidines as scaffolds for multimetallic complexes containing metal-functionalized phosphines

Phosphaguanidines as scaffolds for multimetallic complexes containing metal-functionalized phosphines
Phosphaguanidines as scaffolds for multimetallic complexes containing metal-functionalized phosphines

Phospha(III)guanidines, R2PC{NR′}{NHR′}, have been used to synthesize multimetallic compounds containing combinations of aluminum with platinum or copper, in which the main-group metal is N,N′-bound by an amidinate moiety, thereby generating a metal-functionalized phosphine that bonds to the transition metal through phosphorus.

0020-1669
2258-2260
Grundy, Joanna
0bc72187-8dce-41fc-b809-93a6adbe0980
Mansfield, Natalie E.
4d6b9a06-2b2e-4ba9-916e-8f8ff27c2ac5
Coles, Martyn P.
4cb5ee08-daf9-4b58-9627-61732e0a818b
Hitchcock, Peter B.
4c0fe381-c3e8-452c-a284-fe14acd3b748
Grundy, Joanna
0bc72187-8dce-41fc-b809-93a6adbe0980
Mansfield, Natalie E.
4d6b9a06-2b2e-4ba9-916e-8f8ff27c2ac5
Coles, Martyn P.
4cb5ee08-daf9-4b58-9627-61732e0a818b
Hitchcock, Peter B.
4c0fe381-c3e8-452c-a284-fe14acd3b748

Grundy, Joanna, Mansfield, Natalie E., Coles, Martyn P. and Hitchcock, Peter B. (2008) Phosphaguanidines as scaffolds for multimetallic complexes containing metal-functionalized phosphines. Inorganic Chemistry, 47 (7), 2258-2260. (doi:10.1021/ic7024457).

Record type: Article

Abstract

Phospha(III)guanidines, R2PC{NR′}{NHR′}, have been used to synthesize multimetallic compounds containing combinations of aluminum with platinum or copper, in which the main-group metal is N,N′-bound by an amidinate moiety, thereby generating a metal-functionalized phosphine that bonds to the transition metal through phosphorus.

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More information

e-pub ahead of print date: 23 February 2008
Published date: 7 April 2008

Identifiers

Local EPrints ID: 426203
URI: http://eprints.soton.ac.uk/id/eprint/426203
ISSN: 0020-1669
PURE UUID: 64f15861-c3ea-437a-a6a6-df64bb5f42a1

Catalogue record

Date deposited: 16 Nov 2018 17:30
Last modified: 16 Nov 2018 17:30

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