On the self assembly of a trans-dibromo-bis-(dppfo2) iron (III), a ferrocene-ligand complex, dppfo2 = [(ƞ5-C5H4P(O)Ph2)2Fe]: Letting nature do the work
On the self assembly of a trans-dibromo-bis-(dppfo2) iron (III), a ferrocene-ligand complex, dppfo2 = [(ƞ5-C5H4P(O)Ph2)2Fe]: Letting nature do the work
The octahedral iron complex trans-[{O,O-(ƞ5-C5H4P(O)Ph2)2Fe}2Fe(III)Br2][Fe(III)Br4]has been prepared by self-assembly simply by adding anhydrous ferric chloride to a dichloromethane/methanol solution of dppf and 1,1,2,2-tetrabromoethane and then leaving to form a complex slowly. The key factor in the self-assembly is the addition of 1,1,2,2-tetrabromoethane which is the source of the bromide and is responsible for acid catalysed hydrolysis of ferric chloride.
166-170
Butler, Ian R.
a3e83fb2-442a-47c7-95c8-756a9a5e9f79
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
1 November 2018
Butler, Ian R.
a3e83fb2-442a-47c7-95c8-756a9a5e9f79
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Butler, Ian R., Coles, Simon J. and Horton, Peter N.
(2018)
On the self assembly of a trans-dibromo-bis-(dppfo2) iron (III), a ferrocene-ligand complex, dppfo2 = [(ƞ5-C5H4P(O)Ph2)2Fe]: Letting nature do the work.
Inorganic Chemistry Communications, 97, .
(doi:10.1016/j.inoche.2018.09.010).
Abstract
The octahedral iron complex trans-[{O,O-(ƞ5-C5H4P(O)Ph2)2Fe}2Fe(III)Br2][Fe(III)Br4]has been prepared by self-assembly simply by adding anhydrous ferric chloride to a dichloromethane/methanol solution of dppf and 1,1,2,2-tetrabromoethane and then leaving to form a complex slowly. The key factor in the self-assembly is the addition of 1,1,2,2-tetrabromoethane which is the source of the bromide and is responsible for acid catalysed hydrolysis of ferric chloride.
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Accepted/In Press date: 8 September 2018
e-pub ahead of print date: 15 September 2018
Published date: 1 November 2018
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Local EPrints ID: 426903
URI: http://eprints.soton.ac.uk/id/eprint/426903
ISSN: 1387-7003
PURE UUID: 9c9bdc3c-f3cf-47e1-8ce1-53a30560b951
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Date deposited: 14 Dec 2018 17:30
Last modified: 16 Mar 2024 03:13
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Author:
Ian R. Butler
Author:
Peter N. Horton
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