The University of Southampton
University of Southampton Institutional Repository

On the self assembly of a trans-dibromo-bis-(dppfo2) iron (III), a ferrocene-ligand complex, dppfo2 = [(ƞ5-C5H4P(O)Ph2)2Fe]: Letting nature do the work

On the self assembly of a trans-dibromo-bis-(dppfo2) iron (III), a ferrocene-ligand complex, dppfo2 = [(ƞ5-C5H4P(O)Ph2)2Fe]: Letting nature do the work
On the self assembly of a trans-dibromo-bis-(dppfo2) iron (III), a ferrocene-ligand complex, dppfo2 = [(ƞ5-C5H4P(O)Ph2)2Fe]: Letting nature do the work

The octahedral iron complex trans-[{O,O-(ƞ5-C5H4P(O)Ph2)2Fe}2Fe(III)Br2][Fe(III)Br4]has been prepared by self-assembly simply by adding anhydrous ferric chloride to a dichloromethane/methanol solution of dppf and 1,1,2,2-tetrabromoethane and then leaving to form a complex slowly. The key factor in the self-assembly is the addition of 1,1,2,2-tetrabromoethane which is the source of the bromide and is responsible for acid catalysed hydrolysis of ferric chloride.

1387-7003
166-170
Butler, Ian R.
a3e83fb2-442a-47c7-95c8-756a9a5e9f79
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Butler, Ian R.
a3e83fb2-442a-47c7-95c8-756a9a5e9f79
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5

Butler, Ian R., Coles, Simon J. and Horton, Peter N. (2018) On the self assembly of a trans-dibromo-bis-(dppfo2) iron (III), a ferrocene-ligand complex, dppfo2 = [(ƞ5-C5H4P(O)Ph2)2Fe]: Letting nature do the work. Inorganic Chemistry Communications, 97, 166-170. (doi:10.1016/j.inoche.2018.09.010).

Record type: Article

Abstract

The octahedral iron complex trans-[{O,O-(ƞ5-C5H4P(O)Ph2)2Fe}2Fe(III)Br2][Fe(III)Br4]has been prepared by self-assembly simply by adding anhydrous ferric chloride to a dichloromethane/methanol solution of dppf and 1,1,2,2-tetrabromoethane and then leaving to form a complex slowly. The key factor in the self-assembly is the addition of 1,1,2,2-tetrabromoethane which is the source of the bromide and is responsible for acid catalysed hydrolysis of ferric chloride.

Full text not available from this repository.

More information

Accepted/In Press date: 8 September 2018
e-pub ahead of print date: 15 September 2018
Published date: 1 November 2018

Identifiers

Local EPrints ID: 426903
URI: https://eprints.soton.ac.uk/id/eprint/426903
ISSN: 1387-7003
PURE UUID: 9c9bdc3c-f3cf-47e1-8ce1-53a30560b951
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016

Catalogue record

Date deposited: 14 Dec 2018 17:30
Last modified: 14 Mar 2019 01:48

Export record

Altmetrics

Contributors

Author: Ian R. Butler
Author: Simon J. Coles ORCID iD
Author: Peter N. Horton ORCID iD

University divisions

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of https://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×