The University of Southampton
×
Filter your search:
University of Southampton Institutional Repository

Visible light induced oxidative hydroxylation of boronic acids

Visible light induced oxidative hydroxylation of boronic acids
Visible light induced oxidative hydroxylation of boronic acids

We report herein a visible light-induced aerobic oxidative hydroxylation of boronic acids. The reaction employed 7H-benzo[c]thioxanthen-7-one as metal-free catalyst and dimethyl carbonate as green solvent. Scale-up experiment was achieved using 0.1 mol% catalyst in a good yield with column-free purification. This reaction showed great green chemistry features and potential in synthetic applications.

Boronic acid, Hydroxylation, Oxidation, Photochemistry
0040-4039
660-663
Ding, Aishun
e9d00485-889e-4734-b191-f69d662f53ed
Zhang, Yanbin
1d112312-1a7a-4511-9411-35cab8f6e369
Chen, Yang
375f106d-ff86-4e25-8f73-54f9ad0d06c7
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Hu, Jianhua
738c9ffd-3d98-4972-b6cf-efd88882db8d
Guo, Hao
2e060524-1e5c-47e7-8ee6-b81d25f82d0d
Ding, Aishun
e9d00485-889e-4734-b191-f69d662f53ed
Zhang, Yanbin
1d112312-1a7a-4511-9411-35cab8f6e369
Chen, Yang
375f106d-ff86-4e25-8f73-54f9ad0d06c7
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Hu, Jianhua
738c9ffd-3d98-4972-b6cf-efd88882db8d
Guo, Hao
2e060524-1e5c-47e7-8ee6-b81d25f82d0d

Ding, Aishun, Zhang, Yanbin, Chen, Yang, Rios, Ramon, Hu, Jianhua and Guo, Hao (2019) Visible light induced oxidative hydroxylation of boronic acids. Tetrahedron Letters, 60 (9), 660-663. (doi:10.1016/j.tetlet.2019.01.052).

Record type: Article

Abstract

We report herein a visible light-induced aerobic oxidative hydroxylation of boronic acids. The reaction employed 7H-benzo[c]thioxanthen-7-one as metal-free catalyst and dimethyl carbonate as green solvent. Scale-up experiment was achieved using 0.1 mol% catalyst in a good yield with column-free purification. This reaction showed great green chemistry features and potential in synthetic applications.

Text
TL 2019 660 manuscript - Accepted Manuscript
Available under License Creative Commons Attribution Non-commercial No Derivatives.
Download (165kB)

More information

Accepted/In Press date: 25 January 2019
e-pub ahead of print date: 29 January 2019
Published date: 28 February 2019
Keywords: Boronic acid, Hydroxylation, Oxidation, Photochemistry

Identifiers

Local EPrints ID: 428695
URI: http://eprints.soton.ac.uk/id/eprint/428695
DOI: doi:10.1016/j.tetlet.2019.01.052
ISSN: 0040-4039
PURE UUID: 910168f6-7829-4fd6-9979-b76eeee9f371
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 06 Mar 2019 17:30
Last modified: 18 Mar 2024 05:22

Export record

Altmetrics

Contributors

Author: Aishun Ding
Author: Yanbin Zhang
Author: Yang Chen
Author: Ramon Rios ORCID iD
Author: Jianhua Hu
Author: Hao Guo

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information
Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×