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[GaF3(BzMe2-tacn)] – a neutral ‘metalloligand’ towards alkali metal and ammonium cations in water

[GaF3(BzMe2-tacn)] – a neutral ‘metalloligand’ towards alkali metal and ammonium cations in water
[GaF3(BzMe2-tacn)] – a neutral ‘metalloligand’ towards alkali metal and ammonium cations in water
The neutral complex, [GaF3(L)] (L = 1-benzyl-4,7-dimethyl-1,4,7-triazacyclononane, BzMe2-tacn), acts as a ‘metalloligand’ to Na+, K+ and [NH4]+ cations in aqueous solution, forming supramolecular assemblies containing significant Na/K–F and H3N+H⋯F coordination. κ1-[BF4]− and κ2-[PF6]− coordination is also evident to Na+ and K+, respectively.
1359-7345
12673-12675
Bhalla, Rajiv
685dca44-2474-4fca-a7ea-0075d641e7f2
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Luthra, Sajinder K.
2ad7947e-6a9e-4472-95b4-87274f4d2f54
McRobbie, Graeme
b12f273f-dd78-4ff8-a423-b0b5158091c7
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Sanderson, George
28c458aa-326b-4029-b8cc-cc3035d4acd2
Zhang, Wenjian
1f80ac5e-d4c2-4720-b19e-be700cd411e7
Bhalla, Rajiv
685dca44-2474-4fca-a7ea-0075d641e7f2
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Luthra, Sajinder K.
2ad7947e-6a9e-4472-95b4-87274f4d2f54
McRobbie, Graeme
b12f273f-dd78-4ff8-a423-b0b5158091c7
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Sanderson, George
28c458aa-326b-4029-b8cc-cc3035d4acd2
Zhang, Wenjian
1f80ac5e-d4c2-4720-b19e-be700cd411e7

Bhalla, Rajiv, Levason, William, Luthra, Sajinder K., McRobbie, Graeme, Reid, Gillian, Sanderson, George and Zhang, Wenjian (2014) [GaF3(BzMe2-tacn)] – a neutral ‘metalloligand’ towards alkali metal and ammonium cations in water. Chemical Communications, 50 (84), 12673-12675. (doi:10.1039/C4CC05603E).

Record type: Article

Abstract

The neutral complex, [GaF3(L)] (L = 1-benzyl-4,7-dimethyl-1,4,7-triazacyclononane, BzMe2-tacn), acts as a ‘metalloligand’ to Na+, K+ and [NH4]+ cations in aqueous solution, forming supramolecular assemblies containing significant Na/K–F and H3N+H⋯F coordination. κ1-[BF4]− and κ2-[PF6]− coordination is also evident to Na+ and K+, respectively.

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Accepted/In Press date: 4 September 2014
e-pub ahead of print date: 4 September 2014

Identifiers

Local EPrints ID: 428731
URI: http://eprints.soton.ac.uk/id/eprint/428731
ISSN: 1359-7345
PURE UUID: ace55f92-91c6-4038-86f2-c79f17a6b012
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

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Date deposited: 07 Mar 2019 17:30
Last modified: 07 Oct 2020 01:36

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Contributors

Author: Rajiv Bhalla
Author: William Levason ORCID iD
Author: Sajinder K. Luthra
Author: Graeme McRobbie
Author: Gillian Reid ORCID iD
Author: George Sanderson
Author: Wenjian Zhang

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