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Coordination chemistry and applications of medium/high oxidation state metal and non-metal fluoride and oxide-fluoride complexes with neutral donor ligands

Coordination chemistry and applications of medium/high oxidation state metal and non-metal fluoride and oxide-fluoride complexes with neutral donor ligands
Coordination chemistry and applications of medium/high oxidation state metal and non-metal fluoride and oxide-fluoride complexes with neutral donor ligands
Most high and medium oxidation state (O.S. ≥ 3) metal and non-metal fluorides and oxide fluorides have Lewis acidic properties although detailed exploration of their chemistry with neutral ligands, which differs significantly from that with chloride, bromide or iodide co-ligands, has only been undertaken in recent years. The previous review (Benjamin et. al. Chem. Soc. Rev. 42 (2013) 1460) covered work published up to ~ 2011, and the present article covers new work up to early 2019, a period which has seen many new contributions to the field. This article describes work on the coordination chemistry of d, f and p-block fluorides and oxide fluorides with neutral ligands containing donor atoms drawn from Groups 15 (N, P, As or Sb) and 16 (O, S, Se or Te) and including N-heterocyclic carbenes. The incorporation of the radionuclide 18F into neutral metal complexes and their use in medical diagnosis via positron emission tomography (PET) is described, along with briefer coverage of other potential applications.
fluoride, oxide fluoride, complexes, 18F radiopharmaceuticals
0010-8545
90-130
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Monzittu, Francesco
7c94332d-ed34-4ee6-b8b3-c17c14b11849
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Monzittu, Francesco
7c94332d-ed34-4ee6-b8b3-c17c14b11849
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037

Levason, William, Monzittu, Francesco and Reid, Gillian (2019) Coordination chemistry and applications of medium/high oxidation state metal and non-metal fluoride and oxide-fluoride complexes with neutral donor ligands. Coordination Chemistry Reviews, 391, 90-130. (doi:10.1016/j.ccr.2019.04.005).

Record type: Article

Abstract

Most high and medium oxidation state (O.S. ≥ 3) metal and non-metal fluorides and oxide fluorides have Lewis acidic properties although detailed exploration of their chemistry with neutral ligands, which differs significantly from that with chloride, bromide or iodide co-ligands, has only been undertaken in recent years. The previous review (Benjamin et. al. Chem. Soc. Rev. 42 (2013) 1460) covered work published up to ~ 2011, and the present article covers new work up to early 2019, a period which has seen many new contributions to the field. This article describes work on the coordination chemistry of d, f and p-block fluorides and oxide fluorides with neutral ligands containing donor atoms drawn from Groups 15 (N, P, As or Sb) and 16 (O, S, Se or Te) and including N-heterocyclic carbenes. The incorporation of the radionuclide 18F into neutral metal complexes and their use in medical diagnosis via positron emission tomography (PET) is described, along with briefer coverage of other potential applications.

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MFreview_revised - Accepted Manuscript
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Accepted/In Press date: 14 April 2019
e-pub ahead of print date: 6 May 2019
Published date: 15 July 2019
Keywords: fluoride, oxide fluoride, complexes, 18F radiopharmaceuticals

Identifiers

Local EPrints ID: 430464
URI: http://eprints.soton.ac.uk/id/eprint/430464
ISSN: 0010-8545
PURE UUID: 2ae195b7-7f78-418c-bbc8-a970db0dd54c
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

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Date deposited: 01 May 2019 16:30
Last modified: 18 Feb 2021 16:34

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Author: William Levason ORCID iD
Author: Francesco Monzittu
Author: Gillian Reid ORCID iD

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