Photoionization studies of reactive intermediates using synchrotron radiation: a perspective
Photoionization studies of reactive intermediates using synchrotron radiation: a perspective
Photoionization of reactive intermediates with synchrotron radiation has reached a sufficiently advanced stage of development that it can now contribute to a number of areas in gas-phase chemistry and physics. These include the detection and spectroscopic study of reactive intermediates produced by bimolecular reactions, photolysis, pyrolysis or discharge sources, and the monitoring of reactive intermediates in situ in environments such as flames. This review summarises advances in the study of reactive intermediates with synchrotron radiation using photoelectron spectroscopy (PES) and constant-ionic-state (CIS) methods with angular resolution, and threshold photoelectron spectroscopy (TPES), taking examples mainly from the recent work of the Southampton group. The aim is to focus on the main information to be obtained from the examples considered. As future research in this area also involves photoelectron–photoion coincidence (PEPICO) and threshold photoelectron–photoion coincidence (TPEPICO) spectroscopy, these methods are also described and previous related work on reactive intermediates with these techniques is summarised. The advantages of using PEPICO and TPEPICO to complement and extend TPES and angularly resolved PES and CIS studies on reactive intermediates are highlighted.
9106-9136
Dyke, John
46393b45-6694-46f3-af20-d7369d26199f
Dyke, John
46393b45-6694-46f3-af20-d7369d26199f
Dyke, John
(2019)
Photoionization studies of reactive intermediates using synchrotron radiation: a perspective.
Physical Chemistry Chemical Physics, 2019 (21), .
(doi:10.1039/C9CP00623K).
Abstract
Photoionization of reactive intermediates with synchrotron radiation has reached a sufficiently advanced stage of development that it can now contribute to a number of areas in gas-phase chemistry and physics. These include the detection and spectroscopic study of reactive intermediates produced by bimolecular reactions, photolysis, pyrolysis or discharge sources, and the monitoring of reactive intermediates in situ in environments such as flames. This review summarises advances in the study of reactive intermediates with synchrotron radiation using photoelectron spectroscopy (PES) and constant-ionic-state (CIS) methods with angular resolution, and threshold photoelectron spectroscopy (TPES), taking examples mainly from the recent work of the Southampton group. The aim is to focus on the main information to be obtained from the examples considered. As future research in this area also involves photoelectron–photoion coincidence (PEPICO) and threshold photoelectron–photoion coincidence (TPEPICO) spectroscopy, these methods are also described and previous related work on reactive intermediates with these techniques is summarised. The advantages of using PEPICO and TPEPICO to complement and extend TPES and angularly resolved PES and CIS studies on reactive intermediates are highlighted.
Text
REVIEW FINAL Photoionization
- Accepted Manuscript
Text
FIGURES FINAL for REVIEW
Restricted to Repository staff only
Request a copy
More information
Accepted/In Press date: 5 April 2019
e-pub ahead of print date: 9 April 2019
Identifiers
Local EPrints ID: 431128
URI: http://eprints.soton.ac.uk/id/eprint/431128
ISSN: 1463-9076
PURE UUID: 17f44d78-d260-466f-ad63-dd0b14cf09b8
Catalogue record
Date deposited: 24 May 2019 16:30
Last modified: 16 Mar 2024 07:52
Export record
Altmetrics
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
