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Photo-initiation of ZnO nanorod formation by femtosecond laser irradiation

Photo-initiation of ZnO nanorod formation by femtosecond laser irradiation
Photo-initiation of ZnO nanorod formation by femtosecond laser irradiation
A photo-initiated process via femtosecond pulse induced heterogeneous nucleation in zinc ammine complex (Zn(NH3)42+) based aqueous solution without catalyst and surfactant, followed by thermal treatments for crystal growth into zinc oxide (ZnO) nanorods, was investigated. Hexagonal ZnO nanorods of diameter ≤ 100 nm with smooth planes and length ≤ 1 μm were grown with laser irradiation and successive thermal treatment. The studies show that pH value in the aqueous solutions remarkably effect on morphology of the ZnO nanostructure. Due to the localized high supersaturation of precursor, the hexagonal nucleation was induced by laser irradiation.
Zinc oxide, Nanorods, Laser processing, Ultrafast pulse, Growth mechanism
1882-0743
147-151
Wu, Nan
f26dc0e1-7da9-4c52-a5a8-d6387a8853f2
Shimotsuma, Yasuhiko
0664279b-def2-41d4-a5ec-207ce02013a7
Nishi, Masayuki
4ccdf7c3-f87c-40ab-9069-02eaee4487ce
Sakakura, Masaaki
3bb15bbd-d590-4cba-ab5a-862dc7acd054
Miura, Kiyotaka
5dbc9159-ace0-4dd9-b18d-36f87ae78c47
Hirao, Kazuyuki
5cc5061d-6217-49ae-bc92-ff5b72b9c6c2
Wu, Nan
f26dc0e1-7da9-4c52-a5a8-d6387a8853f2
Shimotsuma, Yasuhiko
0664279b-def2-41d4-a5ec-207ce02013a7
Nishi, Masayuki
4ccdf7c3-f87c-40ab-9069-02eaee4487ce
Sakakura, Masaaki
3bb15bbd-d590-4cba-ab5a-862dc7acd054
Miura, Kiyotaka
5dbc9159-ace0-4dd9-b18d-36f87ae78c47
Hirao, Kazuyuki
5cc5061d-6217-49ae-bc92-ff5b72b9c6c2

Wu, Nan, Shimotsuma, Yasuhiko, Nishi, Masayuki, Sakakura, Masaaki, Miura, Kiyotaka and Hirao, Kazuyuki (2010) Photo-initiation of ZnO nanorod formation by femtosecond laser irradiation. Journal of the Ceramic Society of Japan, 118 (1374), 147-151. (doi:10.2109/jcersj2.118.147).

Record type: Article

Abstract

A photo-initiated process via femtosecond pulse induced heterogeneous nucleation in zinc ammine complex (Zn(NH3)42+) based aqueous solution without catalyst and surfactant, followed by thermal treatments for crystal growth into zinc oxide (ZnO) nanorods, was investigated. Hexagonal ZnO nanorods of diameter ≤ 100 nm with smooth planes and length ≤ 1 μm were grown with laser irradiation and successive thermal treatment. The studies show that pH value in the aqueous solutions remarkably effect on morphology of the ZnO nanostructure. Due to the localized high supersaturation of precursor, the hexagonal nucleation was induced by laser irradiation.

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More information

Published date: February 2010
Additional Information: No Southampton authors at time of publication
Keywords: Zinc oxide, Nanorods, Laser processing, Ultrafast pulse, Growth mechanism

Identifiers

Local EPrints ID: 431161
URI: http://eprints.soton.ac.uk/id/eprint/431161
ISSN: 1882-0743
PURE UUID: 3e442dfe-ad21-4384-85d1-09eb17dce666

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Date deposited: 24 May 2019 16:30
Last modified: 16 Mar 2024 01:56

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Contributors

Author: Nan Wu
Author: Yasuhiko Shimotsuma
Author: Masayuki Nishi
Author: Masaaki Sakakura
Author: Kiyotaka Miura
Author: Kazuyuki Hirao

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