Metal‐free iodine‐mediated deoxygenation of alcohols in the position α to electron‐withdrawing groups

Pichon, Maeva M., Compain, Philippe, Stauffert, Fabien, Bodlenner, Anne and Guillermo Addate-Moya, Luis (2018) Metal‐free iodine‐mediated deoxygenation of alcohols in the position α to electron‐withdrawing groups. European Journal of Organic Chemistry, 2018 (13), 1538-1545. (doi:10.1002/ejoc.201800051).

Record type: Article

Abstract

The use of a substoichiometric amount of molecular iodine in the presence of PPh3 and pyridine effects a direct deoxygenation of primary and secondary alcohols in positions α to a variety of activating electron‐withdrawing groups, including ketones, esters, amides, imides and nitrile groups.

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e-pub ahead of print date: 8 February 2018

Published date: 9 April 2018

Identifiers

Local EPrints ID: 432947

URI: http://eprints.soton.ac.uk/id/eprint/432947

DOI: doi:10.1002/ejoc.201800051

ISSN: 1434-193X

PURE UUID: 4e3f213d-5aab-457e-9174-24c83fcde93c

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Date deposited: 01 Aug 2019 16:30

Last modified: 16 Mar 2024 02:59

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Contributors

Author: Maeva M. Pichon

Author: Philippe Compain

Author: Fabien Stauffert

Author: Anne Bodlenner

Author: Luis Guillermo Addate-Moya

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