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Phenylacetylene hydrogenation on Au@Ni bimetallic core–shell nanoparticles synthesized under mild conditions

Phenylacetylene hydrogenation on Au@Ni bimetallic core–shell nanoparticles synthesized under mild conditions
Phenylacetylene hydrogenation on Au@Ni bimetallic core–shell nanoparticles synthesized under mild conditions
The synthesis of Au@Ni bimetallic core–shell nanoparticles through an energy efficient (lower temperature) route in oleylamine following a sequential reduction strategy is reported. The method is found to be useful for the synthesis of a very thin nickel shell (2 nm) over a gold core (15 nm). Synergistic effects are observed in catalyzing phenylacetylene hydrogenation under different solvent conditions.
2044-4753
708-712
Vysakh, A.B.
da683ba2-fdc2-4bbe-9d31-18ea9f542cad
Lazar, Anish
f01c546a-a2e1-4b7b-a121-dd6e06de6b61
Yadukiran, V.
b9a3f51c-7e24-4ddb-a399-1a84a8ba6cdd
Singh, A.P.
df443df3-4520-4abc-9aff-09160821b030
Vinod, C.P.
69ab3af1-76dd-4e3a-bc39-e97e6b1d4e33
Vysakh, A.B.
da683ba2-fdc2-4bbe-9d31-18ea9f542cad
Lazar, Anish
f01c546a-a2e1-4b7b-a121-dd6e06de6b61
Yadukiran, V.
b9a3f51c-7e24-4ddb-a399-1a84a8ba6cdd
Singh, A.P.
df443df3-4520-4abc-9aff-09160821b030
Vinod, C.P.
69ab3af1-76dd-4e3a-bc39-e97e6b1d4e33

Vysakh, A.B., Lazar, Anish, Yadukiran, V., Singh, A.P. and Vinod, C.P. (2016) Phenylacetylene hydrogenation on Au@Ni bimetallic core–shell nanoparticles synthesized under mild conditions. Catalysis Science & Technology, 6 (3), 708-712. (doi:10.1039/C5CY02005K).

Record type: Article

Abstract

The synthesis of Au@Ni bimetallic core–shell nanoparticles through an energy efficient (lower temperature) route in oleylamine following a sequential reduction strategy is reported. The method is found to be useful for the synthesis of a very thin nickel shell (2 nm) over a gold core (15 nm). Synergistic effects are observed in catalyzing phenylacetylene hydrogenation under different solvent conditions.

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More information

Accepted/In Press date: 5 January 2016
e-pub ahead of print date: 20 January 2016
Published date: 2016

Identifiers

Local EPrints ID: 435387
URI: http://eprints.soton.ac.uk/id/eprint/435387
ISSN: 2044-4753
PURE UUID: 9ca3eecb-8cbe-4f7c-9b39-913b38d74e81

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Date deposited: 01 Nov 2019 17:30
Last modified: 16 Mar 2024 04:47

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Contributors

Author: A.B. Vysakh
Author: Anish Lazar
Author: V. Yadukiran
Author: A.P. Singh
Author: C.P. Vinod

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